Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications

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Abstract

Cooperativity between the Li and Al centres is implicated in catalytic hydroboration reactions of aldehydes and ketones with pinacolborane via heteroleptic lithium diamidodihydridoaluminates. In addition to implementing hydroalumination, these versatile heteroleptic ates can also perform as amido bases as illustrated with an acidic triazole.
LanguageEnglish
Pages1233-1236
Number of pages4
JournalChemical Communications
Volume54
Issue number10
Early online date16 Jan 2018
DOIs
Publication statusPublished - 16 Jan 2018

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Triazoles
Ketones
Aldehydes
Lithium
4,4,5,5-tetramethyl(1,3,2)dioxaborolane

Keywords

  • catalytic hydroboration
  • hydroalumination
  • catalysis

Cite this

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title = "Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications",
abstract = "Cooperativity between the Li and Al centres is implicated in catalytic hydroboration reactions of aldehydes and ketones with pinacolborane via heteroleptic lithium diamidodihydridoaluminates. In addition to implementing hydroalumination, these versatile heteroleptic ates can also perform as amido bases as illustrated with an acidic triazole.",
keywords = "catalytic hydroboration, hydroalumination, catalysis",
author = "Pollard, {Victoria A.} and Orr, {Samantha A.} and Ross McLellan and Kennedy, {Alan R.} and Eva Hevia and Mulvey, {Robert E.}",
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AU - Pollard, Victoria A.

AU - Orr, Samantha A.

AU - McLellan, Ross

AU - Kennedy, Alan R.

AU - Hevia, Eva

AU - Mulvey, Robert E.

PY - 2018/1/16

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N2 - Cooperativity between the Li and Al centres is implicated in catalytic hydroboration reactions of aldehydes and ketones with pinacolborane via heteroleptic lithium diamidodihydridoaluminates. In addition to implementing hydroalumination, these versatile heteroleptic ates can also perform as amido bases as illustrated with an acidic triazole.

AB - Cooperativity between the Li and Al centres is implicated in catalytic hydroboration reactions of aldehydes and ketones with pinacolborane via heteroleptic lithium diamidodihydridoaluminates. In addition to implementing hydroalumination, these versatile heteroleptic ates can also perform as amido bases as illustrated with an acidic triazole.

KW - catalytic hydroboration

KW - hydroalumination

KW - catalysis

UR - http://pubs.rsc.org/en/Journals/JournalIssues/CC

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