Lithium aspirinate hemihydrate

Jean-Baptiste Arlin; Fiona Addison; Alan R. Kennedy

doi:10.1107/S0108270107051104

Lithium aspirinate hemihydrate

Jean-Baptiste Arlin
, Fiona Addison
, Alan R. Kennedy

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The title compound {systematic name: catena-poly[ lithium(I)-mu(3)-acetylsalicylato-hemi-mu(2)-aqua]}, {[Li(C9H7O4)]center dot 0.5H(2)O}(n), is the hemihydrate of the lithium salt of aspirin. The carboxylate groups and water molecules bridge between Li atoms to form a one-dimensional coordination chain composed of two distinct ring types. The water O atom lies on a twofold axis. Hydrogen bonding between water donors and carbonyl acceptors further links the coordination chains to form a sheet structure.

Original language	English
Pages (from-to)	M563-M565
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	63
DOIs	https://doi.org/10.1107/S0108270107051104
Publication status	Published - Dec 2007

Keywords

hydrogen diaspirinate bisacetyIate
crustal structures
monobasic acids
diffraction
salts

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10.1107/S0108270107051104

x-ray diffractometer
Kennedy, A.
Pure And Applied Chemistry
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title = "Lithium aspirinate hemihydrate",

abstract = "The title compound \{systematic name: catena-poly[ lithium(I)-mu(3)-acetylsalicylato-hemi-mu(2)-aqua]\}, \{[Li(C9H7O4)]center dot 0.5H(2)O\}(n), is the hemihydrate of the lithium salt of aspirin. The carboxylate groups and water molecules bridge between Li atoms to form a one-dimensional coordination chain composed of two distinct ring types. The water O atom lies on a twofold axis. Hydrogen bonding between water donors and carbonyl acceptors further links the coordination chains to form a sheet structure.",

keywords = "hydrogen diaspirinate bisacetyIate, crustal structures, monobasic acids, diffraction, salts",

author = "Jean-Baptiste Arlin and Fiona Addison and Kennedy, \{Alan R.\}",

year = "2007",

month = dec,

doi = "10.1107/S0108270107051104",

language = "English",

volume = "63",

pages = "M563--M565",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

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TY - JOUR

T1 - Lithium aspirinate hemihydrate

AU - Arlin, Jean-Baptiste

AU - Addison, Fiona

AU - Kennedy, Alan R.

PY - 2007/12

Y1 - 2007/12

N2 - The title compound {systematic name: catena-poly[ lithium(I)-mu(3)-acetylsalicylato-hemi-mu(2)-aqua]}, {[Li(C9H7O4)]center dot 0.5H(2)O}(n), is the hemihydrate of the lithium salt of aspirin. The carboxylate groups and water molecules bridge between Li atoms to form a one-dimensional coordination chain composed of two distinct ring types. The water O atom lies on a twofold axis. Hydrogen bonding between water donors and carbonyl acceptors further links the coordination chains to form a sheet structure.

AB - The title compound {systematic name: catena-poly[ lithium(I)-mu(3)-acetylsalicylato-hemi-mu(2)-aqua]}, {[Li(C9H7O4)]center dot 0.5H(2)O}(n), is the hemihydrate of the lithium salt of aspirin. The carboxylate groups and water molecules bridge between Li atoms to form a one-dimensional coordination chain composed of two distinct ring types. The water O atom lies on a twofold axis. Hydrogen bonding between water donors and carbonyl acceptors further links the coordination chains to form a sheet structure.

KW - hydrogen diaspirinate bisacetyIate

KW - crustal structures

KW - monobasic acids

KW - diffraction

KW - salts

U2 - 10.1107/S0108270107051104

DO - 10.1107/S0108270107051104

M3 - Article

SN - 0108-2701

VL - 63

SP - M563-M565

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

ER -

Lithium aspirinate hemihydrate

Abstract

Keywords

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