Abstract
| Language | English |
|---|---|
| Pages | 1886-1889 |
| Number of pages | 4 |
| Journal | Organic Letters |
| Volume | 15 |
| Issue number | 8 |
| Early online date | 11 Apr 2013 |
| DOIs | |
| Publication status | Published - 19 Apr 2013 |
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Ligand- and base-free Pd(II)-catalyzed controlled switching between Oxidative Heck and conjugate addition reactions. / Walker, Sarah E.; Boehnke, Julian; Glen, Pauline E.; Levey, Steven; Patrick, Lisa ; Jordan-Hore, James A.; Lee, Ai-Lan.
In: Organic Letters, Vol. 15, No. 8, 19.04.2013, p. 1886-1889.Research output: Contribution to journal › Article
TY - JOUR
T1 - Ligand- and base-free Pd(II)-catalyzed controlled switching between Oxidative Heck and conjugate addition reactions
AU - Walker, Sarah E.
AU - Boehnke, Julian
AU - Glen, Pauline E.
AU - Levey, Steven
AU - Patrick, Lisa
AU - Jordan-Hore, James A.
AU - Lee, Ai-Lan
PY - 2013/4/19
Y1 - 2013/4/19
N2 - A simple change of solvent allows controlled and efficient switching between oxidative Heck and conjugate addition reactions on cyclic Michael acceptor substrates, catalyzed by a cationic Pd(II) catalyst system. Both reactions are ligand- and base-free and tolerant of air and moisture, and the controlled switching sheds light on some of the factors which favor one reaction over the other.
AB - A simple change of solvent allows controlled and efficient switching between oxidative Heck and conjugate addition reactions on cyclic Michael acceptor substrates, catalyzed by a cationic Pd(II) catalyst system. Both reactions are ligand- and base-free and tolerant of air and moisture, and the controlled switching sheds light on some of the factors which favor one reaction over the other.
U2 - 10.1021/ol400539h
DO - 10.1021/ol400539h
M3 - Article
VL - 15
SP - 1886
EP - 1889
JO - Organic Letters
T2 - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 8
ER -