Li-salt functionalised carbon nanotubes as low work function field emitters

Stephen M. Lyth, R. A. Hatton, S. R. P. Silva

Research output: Chapter in Book/Report/Conference proceedingConference contribution book

Abstract

Carbon nanotubes have excellent field emission (FE) properties. The work function (WF) of materials plays a crucial role in their FE properties. From the well known Fowler-Nordheim equation, it is evident that reducing the WF should result in an exponential increase in current density at a given electric field. Therefore, for cold cathode applications it is desirable to minimize the emitter WF without compromising the cathode stability towards oxidation. We have recently shown that the WF of acid-oxidized multiwall carbon nanotubes (o-MWNT) can be reduced by exchanging acidic surface groups with alkali metal cations. In this paper, we report a method for applying o-MWNT onto carbon fibre (CF) fabric from solution and an improvement in the FE properties after converting carboxylic groups to the carboxylate salt of lithium via cation exchange. It is envisaged that this technique could be applied to a wide range of nanotube emitters to reduce the WF and improve the FE properties.
Original languageEnglish
Title of host publication8th IEEE International Vacuum Electronics Conference, IVEC 2007
Place of PublicationPiscataway, NJ
PublisherIEEE
Pages195-196
Number of pages2
ISBN (Print)1424406331, 9781424406333
DOIs
Publication statusPublished - 30 Jul 2007
Externally publishedYes
Event8th IEEE International Vacuum Electronics Conference, IVEC 2007 - Kitakyushu, Japan
Duration: 15 May 200717 May 2007

Conference

Conference8th IEEE International Vacuum Electronics Conference, IVEC 2007
Country/TerritoryJapan
CityKitakyushu
Period15/05/0717/05/07

Keywords

  • carbon nanotubes
  • carbon fibres
  • electron field emission

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