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Abstract
Three Lewis base variations of the synthetically useful
aluminate [L?Li(TMP)(iBu)Al(iBu)2], where L is TMPH, Et3N
or PhC(LO)NiPr2, are reported, together with the reaction of
the benzamide complex with 1,4-dioxane, which surprisingly
leads to fragmentation of the cyclic ether and capture of its alkoxy vinyl ether residue within a novel dilithium dialuminium hexaalkyl aggregate.
Original language | English |
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Pages (from-to) | 2402-2404 |
Number of pages | 3 |
Journal | Chemical Communications (London) |
Issue number | 23 |
DOIs | |
Publication status | Published - Mar 2007 |
Keywords
- Lewis base aluminate
- TMP aluminate
- 4-dioxane
- benzamide complex
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Dive into the research topics of 'Lewis base stabilized lithium TMP-aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane'. Together they form a unique fingerprint.Projects
- 2 Finished
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"INVERSE" COORDINATION: A NEW DESIGN CONCEPT IN SUPRAMOLECULAR INORGANIC CHEMISTRY
Mulvey, R. (Principal Investigator)
EPSRC (Engineering and Physical Sciences Research Council)
1/10/06 → 31/03/10
Project: Research
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Mixed-Metal Molecular Synergy and its Application in Inverse Crown Chemistry
Mulvey, R. (Principal Investigator)
EPSRC (Engineering and Physical Sciences Research Council)
1/01/05 → 31/01/09
Project: Research