Abstract
The η3-aza-allyl complexes [CH3CH2CH2[graphic omitted]·(HMPA)x]n[M = Li,x= 1, (1); M = Na, X= 2, (2)](HMPA = hexamethylphosphoramide) are formed in high yield when HMPA [OP(NMe2)3] is added to the metal imides, [Bun(But)CNM]n; complexes (1) and (2) have been fully characterised by elemental analyses, and by i.r. and n.m.r. (1H, 7Li, 13C) spectroscopies.
Original language | English |
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Pages (from-to) | 1341-1342 |
Number of pages | 2 |
Journal | Journal of the Chemical Society, Chemical Communications |
Issue number | 18 |
DOIs | |
Publication status | Published - 15 Sept 1989 |
Keywords
- alkali metal imides
- spectroscopic solution studies