Lewis-base-dictated structural variations in sodium amide chemistry: X-ray crystal structures of phenyl(2-pyridyl)amidosodium with hexamethylphosphoric triamide (HMPA) and with pentamethyldiethylenetriamine (PMDETA)

P C  ANDREWS; W  CLEGG; Robert Mulvey

doi:10.1002/anie.199014401

Lewis-base-dictated structural variations in sodium amide chemistry: X-ray crystal structures of phenyl(2-pyridyl)amidosodium with hexamethylphosphoric triamide (HMPA) and with pentamethyldiethylenetriamine (PMDETA)

P C ANDREWS, W CLEGG, Robert Mulvey

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Two crystalline adducts of sodium amide 1 and 2 adopt contrasting binuclear structures, as revealed by X-ray diffraction. Thus, the bidentate anions are linked to the Na+ ions in a terminal manner in 1 but in a bridging manner in 2. Each structure also displays unusual donor-acceptor coordinations, with HMPA bridging to Na+ in 1, while only two of the three available PMDETA nitrogen centers complex to Na+ in 2.

Original language	English
Pages (from-to)	1440-1441
Number of pages	2
Journal	Angewandte Chemie International Edition
Volume	29
Issue number	12
DOIs	https://doi.org/10.1002/anie.199014401
Publication status	Published - Dec 1990

Keywords

complexes
ligands
ring
crystalline adducts
crystal structures

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@article{11c565193421441b8fea8e7a32635852,

title = "Lewis-base-dictated structural variations in sodium amide chemistry: X-ray crystal structures of phenyl(2-pyridyl)amidosodium with hexamethylphosphoric triamide (HMPA) and with pentamethyldiethylenetriamine (PMDETA)",

abstract = "Two crystalline adducts of sodium amide 1 and 2 adopt contrasting binuclear structures, as revealed by X-ray diffraction. Thus, the bidentate anions are linked to the Na+ ions in a terminal manner in 1 but in a bridging manner in 2. Each structure also displays unusual donor-acceptor coordinations, with HMPA bridging to Na+ in 1, while only two of the three available PMDETA nitrogen centers complex to Na+ in 2.",

keywords = "complexes, ligands, ring, crystalline adducts , crystal structures",

author = "ANDREWS, {P C} and W CLEGG and Robert Mulvey",

year = "1990",

month = dec,

doi = "10.1002/anie.199014401",

language = "English",

volume = "29",

pages = "1440--1441",

journal = "Angewandte Chemie International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "12",

}

ANDREWS, PC, CLEGG, W & Mulvey, R 1990, 'Lewis-base-dictated structural variations in sodium amide chemistry: X-ray crystal structures of phenyl(2-pyridyl)amidosodium with hexamethylphosphoric triamide (HMPA) and with pentamethyldiethylenetriamine (PMDETA)', Angewandte Chemie International Edition, vol. 29, no. 12, pp. 1440-1441. https://doi.org/10.1002/anie.199014401

Lewis-base-dictated structural variations in sodium amide chemistry: X-ray crystal structures of phenyl(2-pyridyl)amidosodium with hexamethylphosphoric triamide (HMPA) and with pentamethyldiethylenetriamine (PMDETA). / ANDREWS, P C ; CLEGG, W ; Mulvey, Robert.
In: Angewandte Chemie International Edition, Vol. 29, No. 12, 12.1990, p. 1440-1441.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

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AU - CLEGG, W

AU - Mulvey, Robert

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N2 - Two crystalline adducts of sodium amide 1 and 2 adopt contrasting binuclear structures, as revealed by X-ray diffraction. Thus, the bidentate anions are linked to the Na+ ions in a terminal manner in 1 but in a bridging manner in 2. Each structure also displays unusual donor-acceptor coordinations, with HMPA bridging to Na+ in 1, while only two of the three available PMDETA nitrogen centers complex to Na+ in 2.

AB - Two crystalline adducts of sodium amide 1 and 2 adopt contrasting binuclear structures, as revealed by X-ray diffraction. Thus, the bidentate anions are linked to the Na+ ions in a terminal manner in 1 but in a bridging manner in 2. Each structure also displays unusual donor-acceptor coordinations, with HMPA bridging to Na+ in 1, while only two of the three available PMDETA nitrogen centers complex to Na+ in 2.

KW - complexes

KW - ligands

KW - ring

KW - crystalline adducts

KW - crystal structures

U2 - 10.1002/anie.199014401

DO - 10.1002/anie.199014401

M3 - Article

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