Layer-by-layer self-assembly of bisdendrons: an unprecedented route to multilayer thin films

Ok-Joo Lee; Valérie Maraval; Anne-Marie Caminade; Kyungwha Chung; King Hang Aaron Lau; Kwanwoo Shin; Jean-Pierre Majoral; Wolfgang Knoll; Dong Ha Kim

doi:10.1007/s13233-016-4128-z

Layer-by-layer self-assembly of bisdendrons: an unprecedented route to multilayer thin films

Ok-Joo Lee, Valérie Maraval, Anne-Marie Caminade, Kyungwha Chung, King Hang Aaron Lau, Kwanwoo Shin, Jean-Pierre Majoral, Wolfgang Knoll, Dong Ha Kim

Pure And Applied Chemistry

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Abstract

We present an unprecedented route to fabricate multilayer thin films by single component layer-by-layer molecular self-assembly. Tailored water-soluble phosphorus bisdendrons were obtained via core to core assembling of two dendrons bearing anionic groups at one end and quaternizable amino end groups at the other end. Adsorption of a 1st bisdendron monolayer on a charged substrate followed by sequential quaternization/deposition of a 2nd layer leads to a stepwise growth of multilayers. By this way homogeneous multilayer thin films were successfully constructed as confirmed by spectroscopic and microscopic analysis.

Original language	English
Pages (from-to)	851-855
Number of pages	5
Journal	Macromolecular Research
Volume	24
Issue number	10
Early online date	1 Sept 2016
DOIs	https://doi.org/10.1007/s13233-016-4128-z
Publication status	Published - 31 Oct 2016

Keywords

bisendron
layer-by-layer self-assembly
multilayer thin films
surface plasmon resonance spectroscopy
nanofabrication

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title = "Layer-by-layer self-assembly of bisdendrons: an unprecedented route to multilayer thin films",

abstract = "We present an unprecedented route to fabricate multilayer thin films by single component layer-by-layer molecular self-assembly. Tailored water-soluble phosphorus bisdendrons were obtained via core to core assembling of two dendrons bearing anionic groups at one end and quaternizable amino end groups at the other end. Adsorption of a 1st bisdendron monolayer on a charged substrate followed by sequential quaternization/deposition of a 2nd layer leads to a stepwise growth of multilayers. By this way homogeneous multilayer thin films were successfully constructed as confirmed by spectroscopic and microscopic analysis.",

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doi = "10.1007/s13233-016-4128-z",

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journal = "Macromolecular Research",

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T1 - Layer-by-layer self-assembly of bisdendrons

T2 - an unprecedented route to multilayer thin films

AU - Lee, Ok-Joo

AU - Maraval, Valérie

AU - Caminade, Anne-Marie

AU - Chung, Kyungwha

AU - Lau, King Hang Aaron

AU - Shin, Kwanwoo

AU - Majoral, Jean-Pierre

AU - Knoll, Wolfgang

AU - Kim, Dong Ha

N1 - The final publication is available at Springer via http://link.springer.com/journal/13233

PY - 2016/10/31

Y1 - 2016/10/31

N2 - We present an unprecedented route to fabricate multilayer thin films by single component layer-by-layer molecular self-assembly. Tailored water-soluble phosphorus bisdendrons were obtained via core to core assembling of two dendrons bearing anionic groups at one end and quaternizable amino end groups at the other end. Adsorption of a 1st bisdendron monolayer on a charged substrate followed by sequential quaternization/deposition of a 2nd layer leads to a stepwise growth of multilayers. By this way homogeneous multilayer thin films were successfully constructed as confirmed by spectroscopic and microscopic analysis.

AB - We present an unprecedented route to fabricate multilayer thin films by single component layer-by-layer molecular self-assembly. Tailored water-soluble phosphorus bisdendrons were obtained via core to core assembling of two dendrons bearing anionic groups at one end and quaternizable amino end groups at the other end. Adsorption of a 1st bisdendron monolayer on a charged substrate followed by sequential quaternization/deposition of a 2nd layer leads to a stepwise growth of multilayers. By this way homogeneous multilayer thin films were successfully constructed as confirmed by spectroscopic and microscopic analysis.

KW - bisendron

KW - layer-by-layer self-assembly

KW - multilayer thin films

KW - surface plasmon resonance spectroscopy

KW - nanofabrication

UR - http://link.springer.com/journal/13233

U2 - 10.1007/s13233-016-4128-z

DO - 10.1007/s13233-016-4128-z

M3 - Article

SN - 1598-5032

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SP - 851

EP - 855

JO - Macromolecular Research

JF - Macromolecular Research

IS - 10

ER -

Layer-by-layer self-assembly of bisdendrons: an unprecedented route to multilayer thin films

Abstract

Keywords

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