We present a phenomenological theory for the homogeneous phases of nematic liquid crystals constituted by biaxial molecules. We propose a general polynomial potential in two macroscopic order parameter tensors that reproduces the mean-field phase diagram confirmed by Monte Carlo simulations [De Matteis et al. in Phys Rev E 72:041706 (2005)] and recently recognized to be universal [Bisi et al. in Phys Rev E 73:051709 (2006)] for dispersion force molecular pair-potentials enjoying the D 2h symmetry. The requirement that the phenomenological theory comply uniquely with this phase diagram reduces considerably the admissible phenomenological coefficients, both in their number and in the ranges where they can vary.
- biaxial liquid crystals
- nematic phases
- landau theory
De Matteis, G., Sonnet, A. M., & Virga, E. G. (2008). Landau theory for biaxial nematic liquid crystals with two order parameter tensors. Continuum Mechanics and Thermodynamics, 20(6), 347-374. https://doi.org/10.1007/s00161-008-0086-9