Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences

D R  ARMSTRONG; D  BARR; W  CLEGG; S M  HODGSON; Robert Mulvey; D  REED; R  SNAITH; D S  WRIGHT

doi:10.1021/ja00195a027

Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences

D R ARMSTRONG
, D BARR
, W CLEGG
, S M HODGSON
, Robert Mulvey
, D REED
, R SNAITH
, D S WRIGHT

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

110 Citations (Scopus)

Abstract

Describes ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences.

Original language	English
Pages (from-to)	4719-4727
Number of pages	9
Journal	Journal of the American Chemical Society
Volume	111
Issue number	13
DOIs	https://doi.org/10.1021/ja00195a027
Publication status	Published - 21 Jun 1989

Keywords

ladder structures
lithium amide chemistry
pyrrolidide complexes

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10.1021/ja00195a027

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ARMSTRONG, D. R., BARR, D., CLEGG, W., HODGSON, S. M., Mulvey, R., REED, D., SNAITH, R., & WRIGHT, D. S. (1989). Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences. Journal of the American Chemical Society, 111(13), 4719-4727. https://doi.org/10.1021/ja00195a027

ARMSTRONG, D R ; BARR, D ; CLEGG, W et al. / Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences. In: Journal of the American Chemical Society. 1989 ; Vol. 111, No. 13. pp. 4719-4727.

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title = "Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] \{[H2C(CH2)3NLi]3.cntdot.PMDETA\}2 and [cyclic] \{[H2C(CH2)3NLi]2.cntdot.TMEDA\}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences",

abstract = "Describes ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] \{[H2C(CH2)3NLi]3.cntdot.PMDETA\}2 and [cyclic] \{[H2C(CH2)3NLi]2.cntdot.TMEDA\}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences.",

keywords = "ladder structures, lithium amide chemistry , pyrrolidide complexes",

author = "ARMSTRONG, \{D R\} and D BARR and W CLEGG and HODGSON, \{S M\} and Robert Mulvey and D REED and R SNAITH and WRIGHT, \{D S\}",

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ARMSTRONG, DR, BARR, D, CLEGG, W, HODGSON, SM, Mulvey, R, REED, D, SNAITH, R & WRIGHT, DS 1989, 'Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences', Journal of the American Chemical Society, vol. 111, no. 13, pp. 4719-4727. https://doi.org/10.1021/ja00195a027

Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences. / ARMSTRONG, D R ; BARR, D ; CLEGG, W et al.
In: Journal of the American Chemical Society, Vol. 111, No. 13, 21.06.1989, p. 4719-4727.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

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AU - ARMSTRONG, D R

AU - BARR, D

AU - CLEGG, W

AU - HODGSON, S M

AU - Mulvey, Robert

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AU - SNAITH, R

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AB - Describes ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences.

KW - ladder structures

KW - lithium amide chemistry

KW - pyrrolidide complexes

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ARMSTRONG DR, BARR D, CLEGG W, HODGSON SM, Mulvey R, REED D et al. Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences. Journal of the American Chemical Society. 1989 Jun 21;111(13):4719-4727. doi: 10.1021/ja00195a027