Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences

D R ARMSTRONG, D BARR, W CLEGG, S M HODGSON, Robert Mulvey, D REED, R SNAITH, D S WRIGHT

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Abstract

Describes ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences.
LanguageEnglish
Pages4719-4727
Number of pages9
JournalJournal of the American Chemical Society
Volume111
Issue number13
DOIs
Publication statusPublished - 21 Jun 1989

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Ladders
Lithium
Amides
phenyllithium

Keywords

  • ladder structures
  • lithium amide chemistry
  • pyrrolidide complexes

Cite this

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title = "Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences",
abstract = "Describes ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences.",
keywords = "ladder structures, lithium amide chemistry , pyrrolidide complexes",
author = "ARMSTRONG, {D R} and D BARR and W CLEGG and HODGSON, {S M} and Robert Mulvey and D REED and R SNAITH and WRIGHT, {D S}",
year = "1989",
month = "6",
day = "21",
doi = "10.1021/ja00195a027",
language = "English",
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pages = "4719--4727",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
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TY - JOUR

T1 - Ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences

AU - ARMSTRONG, D R

AU - BARR, D

AU - CLEGG, W

AU - HODGSON, S M

AU - Mulvey, Robert

AU - REED, D

AU - SNAITH, R

AU - WRIGHT, D S

PY - 1989/6/21

Y1 - 1989/6/21

N2 - Describes ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences.

AB - Describes ladder structures in lithium amide chemistry: syntheses, solid-state, and solution structures of donor-deficient lithium pyrrolidide complexes, [cyclic] {[H2C(CH2)3NLi]3.cntdot.PMDETA}2 and [cyclic] {[H2C(CH2)3NLi]2.cntdot.TMEDA}2, and ab initio MO calculations probing ring vs ladder vs stack structural preferences.

KW - ladder structures

KW - lithium amide chemistry

KW - pyrrolidide complexes

U2 - 10.1021/ja00195a027

DO - 10.1021/ja00195a027

M3 - Article

VL - 111

SP - 4719

EP - 4727

JO - Journal of the American Chemical Society

T2 - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

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