Kinetics of iminium ion catalysis

Gareth Evans; Timothy J. K. Gibbs; Robert L. Jenkins; Simon J. Coles; Michael B. Hursthouse; James A. Platts; Nicholas C. O. Tomkinson

doi:10.1002/anie.200705539

Kinetics of iminium ion catalysis

Gareth Evans, Timothy J. K. Gibbs, Robert L. Jenkins, Simon J. Coles, Michael B. Hursthouse, James A. Platts, Nicholas C. O. Tomkinson

Pure And Applied Chemistry

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Abstract

Kinetic and computational data for the key steps of the iminium ion catalyzed Diels-Alder reaction show that the cycloaddn. is the rate-detg. step of the catalytic cycle and provide a rationale for developing more-active catalyst architectures.

Original language	English
Pages (from-to)	2820-2823
Number of pages	4
Journal	Agewandte Chemie-International Edition
Volume	47
Issue number	15
DOIs	https://doi.org/10.1002/anie.200705539
Publication status	Published - 31 Mar 2008

Keywords

iminium ion catalysis
kinetics

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10.1002/anie.200705539

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title = "Kinetics of iminium ion catalysis",

abstract = "Kinetic and computational data for the key steps of the iminium ion catalyzed Diels-Alder reaction show that the cycloaddn. is the rate-detg. step of the catalytic cycle and provide a rationale for developing more-active catalyst architectures. ",

keywords = "iminium ion catalysis , kinetics",

author = "Gareth Evans and Gibbs, \{Timothy J. K.\} and Jenkins, \{Robert L.\} and Coles, \{Simon J.\} and Hursthouse, \{Michael B.\} and Platts, \{James A.\} and Tomkinson, \{Nicholas C. O.\}",

year = "2008",

month = mar,

day = "31",

doi = "10.1002/anie.200705539",

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AU - Evans, Gareth

AU - Gibbs, Timothy J. K.

AU - Jenkins, Robert L.

AU - Coles, Simon J.

AU - Hursthouse, Michael B.

AU - Platts, James A.

AU - Tomkinson, Nicholas C. O.

PY - 2008/3/31

Y1 - 2008/3/31

N2 - Kinetic and computational data for the key steps of the iminium ion catalyzed Diels-Alder reaction show that the cycloaddn. is the rate-detg. step of the catalytic cycle and provide a rationale for developing more-active catalyst architectures.

AB - Kinetic and computational data for the key steps of the iminium ion catalyzed Diels-Alder reaction show that the cycloaddn. is the rate-detg. step of the catalytic cycle and provide a rationale for developing more-active catalyst architectures.

KW - iminium ion catalysis

KW - kinetics

U2 - 10.1002/anie.200705539

DO - 10.1002/anie.200705539

M3 - Article

SN - 1433-7851

VL - 47

SP - 2820

EP - 2823

JO - Agewandte Chemie-International Edition

JF - Agewandte Chemie-International Edition

IS - 15

ER -

Kinetics of iminium ion catalysis

Abstract

Keywords

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