Kinetics of iminium ion catalysis

Gareth Evans, Timothy J. K. Gibbs, Robert L. Jenkins, Simon J. Coles, Michael B. Hursthouse, James A. Platts, Nicholas C. O. Tomkinson

Research output: Contribution to journalArticlepeer-review

34 Citations (Scopus)
12 Downloads (Pure)

Abstract

Kinetic and computational data for the key steps of the iminium ion catalyzed Diels-Alder reaction show that the cycloaddn. is the rate-detg. step of the catalytic cycle and provide a rationale for developing more-active catalyst architectures.
Original languageEnglish
Pages (from-to)2820-2823
Number of pages4
JournalAgewandte Chemie-International Edition
Volume47
Issue number15
DOIs
Publication statusPublished - 31 Mar 2008

Keywords

  • iminium ion catalysis
  • kinetics

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