Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates

X.Y. He; B.C. Noll; A. Beatty; R.E. Mulvey; K.W. Henderson

doi:10.1021/ja048750m

Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates

X.Y. He
, B.C. Noll
, A. Beatty
, R.E. Mulvey
, K.W. Henderson

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

90 Citations (Scopus)

Abstract

Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.

Original language	English
Pages (from-to)	7444-7445
Number of pages	1
Journal	Journal of the American Chemical Society
Volume	126
Issue number	24
DOIs	https://doi.org/10.1021/ja048750m
Publication status	Published - 23 Jun 2004

Keywords

inverse crown chemistry
magnesium
polymerization
complexes
diisopropylamides
alkoxides
sodium

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10.1021/ja048750m

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title = "Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates",

abstract = "Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.",

keywords = "inverse crown chemistry, magnesium, polymerization, complexes, diisopropylamides, alkoxides, sodium",

author = "X.Y. He and B.C. Noll and A. Beatty and R.E. Mulvey and K.W. Henderson",

year = "2004",

month = jun,

day = "23",

doi = "10.1021/ja048750m",

language = "English",

volume = "126",

pages = "7444--7445",

journal = "Journal of the American Chemical Society",

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publisher = "American Chemical Society",

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Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates. / He, X.Y.; Noll, B.C.; Beatty, A. et al.
In: Journal of the American Chemical Society, Vol. 126, No. 24, 23.06.2004, p. 7444-7445.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates

AU - He, X.Y.

AU - Noll, B.C.

AU - Beatty, A.

AU - Mulvey, R.E.

AU - Henderson, K.W.

PY - 2004/6/23

Y1 - 2004/6/23

N2 - Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.

AB - Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.

KW - inverse crown chemistry

KW - magnesium

KW - polymerization

KW - complexes

KW - diisopropylamides

KW - alkoxides

KW - sodium

UR - http://pubs.acs.org/cgi-bin/article.cgi/jacsat/2004/126/i24/pdf/ja048750m.pdf

UR - http://dx.doi.org/10.1021/ja048750m

U2 - 10.1021/ja048750m

DO - 10.1021/ja048750m

M3 - Article

SN - 0002-7863

VL - 126

SP - 7444

EP - 7445

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 24

ER -

Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates

Abstract

Keywords

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