Abstract
Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.
| Original language | English |
|---|---|
| Pages (from-to) | 7444-7445 |
| Number of pages | 1 |
| Journal | Journal of the American Chemical Society |
| Volume | 126 |
| Issue number | 24 |
| DOIs | |
| Publication status | Published - 23 Jun 2004 |
Keywords
- inverse crown chemistry
- magnesium
- polymerization
- complexes
- diisopropylamides
- alkoxides
- sodium
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He, X. Y., Noll, B. C., Beatty, A., Mulvey, R. E., & Henderson, K. W. (2004). Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates. Journal of the American Chemical Society, 126(24), 7444-7445. https://doi.org/10.1021/ja048750m