Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates

X.Y. He, B.C. Noll, A. Beatty, R.E. Mulvey, K.W. Henderson

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Abstract

Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.
LanguageEnglish
Pages7444-7445
Number of pages1
JournalJournal of the American Chemical Society
Volume126
Issue number24
DOIs
Publication statusPublished - 23 Jun 2004

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Alkaline Earth Metals
Alkaline earth metals
Deprotonation
Alkalies
Ketones
Amides
Potassium
Calcium

Keywords

  • inverse crown chemistry
  • magnesium
  • polymerization
  • complexes
  • diisopropylamides
  • alkoxides
  • sodium

Cite this

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title = "Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates",
abstract = "Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.",
keywords = "inverse crown chemistry, magnesium, polymerization, complexes, diisopropylamides, alkoxides, sodium",
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AU - He, X.Y.

AU - Noll, B.C.

AU - Beatty, A.

AU - Mulvey, R.E.

AU - Henderson, K.W.

PY - 2004/6/23

Y1 - 2004/6/23

N2 - Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.

AB - Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.

KW - inverse crown chemistry

KW - magnesium

KW - polymerization

KW - complexes

KW - diisopropylamides

KW - alkoxides

KW - sodium

UR - http://pubs.acs.org/cgi-bin/article.cgi/jacsat/2004/126/i24/pdf/ja048750m.pdf

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