Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates

X.Y. He, B.C. Noll, A. Beatty, R.E. Mulvey, K.W. Henderson

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78 Citations (Scopus)

Abstract

Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.
Original languageEnglish
Pages (from-to)7444-7445
Number of pages1
JournalJournal of the American Chemical Society
Volume126
Issue number24
DOIs
Publication statusPublished - 23 Jun 2004

Keywords

  • inverse crown chemistry
  • magnesium
  • polymerization
  • complexes
  • diisopropylamides
  • alkoxides
  • sodium

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