Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns

E. Hevia, D.J. Gallagher, A.R. Kennedy, R.E. Mulvey, C.T. O'Hara, C. Talmard

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Abstract

Only two-fold amination occurs when 3 molar equivalents of TMPH are offered to a 1:1 BuNa-Bu2Mg mixture; adding TMEDA gives the mixed alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP) Mg(TMP)], which itself affords the phenyl-bridged analogue when reacted with benzene.
LanguageEnglish
Pages2422-2423
Number of pages1
JournalChemical Communications (London)
Volume2004
Issue number21
DOIs
Publication statusPublished - 23 Sep 2004

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Thymidine Monophosphate
Amides
Metals
Amination
Benzene

Keywords

  • magnesium
  • chemistry
  • mixed-metal alkyl amide

Cite this

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abstract = "Only two-fold amination occurs when 3 molar equivalents of TMPH are offered to a 1:1 BuNa-Bu2Mg mixture; adding TMEDA gives the mixed alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP) Mg(TMP)], which itself affords the phenyl-bridged analogue when reacted with benzene.",
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T1 - Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns

AU - Hevia, E.

AU - Gallagher, D.J.

AU - Kennedy, A.R.

AU - Mulvey, R.E.

AU - O'Hara, C.T.

AU - Talmard, C.

PY - 2004/9/23

Y1 - 2004/9/23

N2 - Only two-fold amination occurs when 3 molar equivalents of TMPH are offered to a 1:1 BuNa-Bu2Mg mixture; adding TMEDA gives the mixed alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP) Mg(TMP)], which itself affords the phenyl-bridged analogue when reacted with benzene.

AB - Only two-fold amination occurs when 3 molar equivalents of TMPH are offered to a 1:1 BuNa-Bu2Mg mixture; adding TMEDA gives the mixed alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP) Mg(TMP)], which itself affords the phenyl-bridged analogue when reacted with benzene.

KW - magnesium

KW - chemistry

KW - mixed-metal alkyl amide

UR - http://www.rsc.org/ej/CC/2004/b410293b.pdf

UR - http://dx.doi.org/10.1039/b410293b

U2 - 10.1039/b410293b

DO - 10.1039/b410293b

M3 - Article

VL - 2004

SP - 2422

EP - 2423

JO - Chemical Communications (London)

T2 - Chemical Communications (London)

JF - Chemical Communications (London)

SN - 0009-241X

IS - 21

ER -