Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 4975-4977 |
| Number of pages | 2 |
| Journal | Dalton Transactions |
| Issue number | 37 |
| DOIs | |
| Publication status | Published - 2008 |
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Keywords
- metal mediated magnesiation
- deprotonation
- manganation
- lithiation
- chemistry
- reagents
- diamines
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Isolation and characterisation of a (-)-sparteine coordinated mixed alkyl/ amido sodium magnesiate, a chiral variant of an important utility ate base. / Kennedy, A.R.; O'Hara, C.T.
In: Dalton Transactions, No. 37, 2008, p. 4975-4977.Research output: Contribution to journal › Article
TY - JOUR
T1 - Isolation and characterisation of a (-)-sparteine coordinated mixed alkyl/ amido sodium magnesiate, a chiral variant of an important utility ate base
AU - Kennedy, A.R.
AU - O'Hara, C.T.
PY - 2008
Y1 - 2008
N2 - When a 1 : 1 (BuNa)-Bu-n-(Bu2Mg)-Bu-n,s mixture is treated with two molar equivalents of TMP(H) (TMP = 2,2,6,6-tetramethyl-piperidide) and one molar equivalent of (-)-sparteine in hydrocarbon medium, a new chiral mixed-metal, mixed alkylamide [{(-)-sparteine}center dot Na(mu-Bu)(mu-TMP)Mg(TMP)] can be isolated.
AB - When a 1 : 1 (BuNa)-Bu-n-(Bu2Mg)-Bu-n,s mixture is treated with two molar equivalents of TMP(H) (TMP = 2,2,6,6-tetramethyl-piperidide) and one molar equivalent of (-)-sparteine in hydrocarbon medium, a new chiral mixed-metal, mixed alkylamide [{(-)-sparteine}center dot Na(mu-Bu)(mu-TMP)Mg(TMP)] can be isolated.
KW - metal mediated magnesiation
KW - deprotonation
KW - manganation
KW - lithiation
KW - chemistry
KW - reagents
KW - diamines
UR - http://dx.doi.org/10.1039/b812085b
U2 - 10.1039/b812085b
DO - 10.1039/b812085b
M3 - Article
SP - 4975
EP - 4977
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 37
ER -