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Abstract
When a 1 : 1 (BuNa)-Bu-n-(Bu2Mg)-Bu-n,s mixture is treated with two molar equivalents of TMP(H) (TMP = 2,2,6,6-tetramethyl-piperidide) and one molar equivalent of (-)-sparteine in hydrocarbon medium, a new chiral mixed-metal, mixed alkylamide [{(-)-sparteine}center dot Na(mu-Bu)(mu-TMP)Mg(TMP)] can be isolated.
Original language | English |
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Pages (from-to) | 4975-4977 |
Number of pages | 2 |
Journal | Dalton Transactions |
Issue number | 37 |
DOIs | |
Publication status | Published - 2008 |
Keywords
- metal mediated magnesiation
- deprotonation
- manganation
- lithiation
- chemistry
- reagents
- diamines
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Projects
- 1 Finished