Iridium(I) NHC/phosphine catalysts for mild and chemoselective hydrogenation processes

William J. Kerr, Richard J. Mudd, Jack A. Brown

Research output: Contribution to journal › Article

11 Citations (Scopus)

Abstract

The directed, chemoselective hydrogenation of olefins has been established using iridium(I) catalysts which feature a tuned NHC/phosphine ligand combination. This selective reduction process has been demonstrated in a wide array of solvents, including more environmentally acceptable media, also allowing further refinement of hydrogenation selectivity.
LanguageEnglish
Pages4738–4742
Number of pages5
JournalChemistry - A European Journal
Volume22
Issue number14
Early online date23 Feb 2016
DOIs
Publication statusPublished - 1 Mar 2016

Fingerprint

phosphine
Iridium
Hydrogenation
Catalysts
Alkenes
Ligands

Keywords

  • iridium
  • catalysis
  • hydrogenation
  • reduction
  • chemoselectivity

Cite this

Kerr, William J. ; Mudd, Richard J. ; Brown, Jack A. / Iridium(I) NHC/phosphine catalysts for mild and chemoselective hydrogenation processes. In: Chemistry - A European Journal. 2016 ; Vol. 22, No. 14. pp. 4738–4742.
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Kerr, WJ, Mudd, RJ & Brown, JA 2016, 'Iridium(I) NHC/phosphine catalysts for mild and chemoselective hydrogenation processes' Chemistry - A European Journal, vol. 22, no. 14, pp. 4738–4742. https://doi.org/10.1002/chem.201504825

Iridium(I) NHC/phosphine catalysts for mild and chemoselective hydrogenation processes. / Kerr, William J.; Mudd, Richard J.; Brown, Jack A.

In: Chemistry - A European Journal, Vol. 22, No. 14, 01.03.2016, p. 4738–4742.

Research output: Contribution to journal › Article

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AU - Kerr, William J.

AU - Mudd, Richard J.

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AB - The directed, chemoselective hydrogenation of olefins has been established using iridium(I) catalysts which feature a tuned NHC/phosphine ligand combination. This selective reduction process has been demonstrated in a wide array of solvents, including more environmentally acceptable media, also allowing further refinement of hydrogenation selectivity.

KW - iridium

KW - catalysis

KW - hydrogenation

KW - reduction

KW - chemoselectivity

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Kerr WJ, Mudd RJ, Brown JA. Iridium(I) NHC/phosphine catalysts for mild and chemoselective hydrogenation processes. Chemistry - A European Journal. 2016 Mar 1;22(14):4738–4742. https://doi.org/10.1002/chem.201504825

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