Iridium(I) NHC/phosphine catalysts for mild and chemoselective hydrogenation processes

William J. Kerr; Richard J. Mudd; Jack A. Brown

doi:10.1002/chem.201504825

Iridium(I) NHC/phosphine catalysts for mild and chemoselective hydrogenation processes

William J. Kerr, Richard J. Mudd, Jack A. Brown

Pure And Applied Chemistry

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Abstract

The directed, chemoselective hydrogenation of olefins has been established using iridium(I) catalysts which feature a tuned NHC/phosphine ligand combination. This selective reduction process has been demonstrated in a wide array of solvents, including more environmentally acceptable media, also allowing further refinement of hydrogenation selectivity.

Original language	English
Pages (from-to)	4738–4742
Number of pages	5
Journal	Chemistry - A European Journal
Volume	22
Issue number	14
Early online date	23 Feb 2016
DOIs	https://doi.org/10.1002/chem.201504825
Publication status	Published - 1 Mar 2016

Keywords

iridium
catalysis
hydrogenation
reduction
chemoselectivity

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10.1002/chem.201504825

Kerr-etal-CEJ-2016-Iridium-I-NHC-phosphine-catalysts-for-mild-and-chemoselectiveAccepted author manuscript, 1.33 MB

Cite this

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title = "Iridium(I) NHC/phosphine catalysts for mild and chemoselective hydrogenation processes",

abstract = "The directed, chemoselective hydrogenation of olefins has been established using iridium(I) catalysts which feature a tuned NHC/phosphine ligand combination. This selective reduction process has been demonstrated in a wide array of solvents, including more environmentally acceptable media, also allowing further refinement of hydrogenation selectivity.",

keywords = "iridium, catalysis, hydrogenation, reduction, chemoselectivity",

author = "Kerr, {William J.} and Mudd, {Richard J.} and Brown, {Jack A.}",

year = "2016",

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AU - Kerr, William J.

AU - Mudd, Richard J.

AU - Brown, Jack A.

PY - 2016/3/1

Y1 - 2016/3/1

N2 - The directed, chemoselective hydrogenation of olefins has been established using iridium(I) catalysts which feature a tuned NHC/phosphine ligand combination. This selective reduction process has been demonstrated in a wide array of solvents, including more environmentally acceptable media, also allowing further refinement of hydrogenation selectivity.

AB - The directed, chemoselective hydrogenation of olefins has been established using iridium(I) catalysts which feature a tuned NHC/phosphine ligand combination. This selective reduction process has been demonstrated in a wide array of solvents, including more environmentally acceptable media, also allowing further refinement of hydrogenation selectivity.

KW - iridium

KW - catalysis

KW - hydrogenation

KW - reduction

KW - chemoselectivity

UR - http://onlinelibrary.wiley.com/journal/10.1002/%28ISSN%291521-3765

U2 - 10.1002/chem.201504825

DO - 10.1002/chem.201504825

M3 - Article

SN - 0947-6539

VL - 22

SP - 4738

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JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 14

ER -

Iridium(I) NHC/phosphine catalysts for mild and chemoselective hydrogenation processes

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William Kerr

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Iridium(I) NHC/phosphine catalysts for mild and chemoselective hydrogenation processes

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William Kerr

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