Iridium(I) hydroxides in catalysis: rearrangement of allylic alcohols to ketones

David J Nelson; José A Fernández-Salas; Byron J Truscott; Steven P. Nolan

doi:10.1039/C4OB01428F

Iridium(I) hydroxides in catalysis: rearrangement of allylic alcohols to ketones

David J Nelson, José A Fernández-Salas, Byron J Truscott, Steven P. Nolan

Pure And Applied Chemistry

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Abstract

The iridium(I) hydroxide complex [Ir(OH)(COD)(IiPr)] has been shown to be a competent catalyst for the rearrangement of allylic alcohols to ketones. Reactions proceed in short reaction times (1 − 1.5 h) with microwave heating, in the absence of additives.

Original language	English
Journal	Organic and Biomolecular Chemistry
Early online date	15 Jul 2014
DOIs	https://doi.org/10.1039/C4OB01428F
Publication status	Published - 2014

Keywords

iridium (i)-hydroxide
allylic alcohols
microwave heating

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10.1039/C4OB01428F

Nelson-etal-OBC2014-iridium-i-hydroxides-in-catalysisAccepted author manuscript, 225 KB

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title = "Iridium(I) hydroxides in catalysis: rearrangement of allylic alcohols to ketones",

abstract = "The iridium(I) hydroxide complex [Ir(OH)(COD)(IiPr)] has been shown to be a competent catalyst for the rearrangement of allylic alcohols to ketones. Reactions proceed in short reaction times (1 − 1.5 h) with microwave heating, in the absence of additives. ",

keywords = "iridium (i)-hydroxide, allylic alcohols, microwave heating",

author = "Nelson, {David J} and Fern{\'a}ndez-Salas, {Jos{\'e} A} and Truscott, {Byron J} and Nolan, {Steven P.}",

year = "2014",

doi = "10.1039/C4OB01428F",

language = "English",

journal = "Organic and Biomolecular Chemistry",

issn = "1477-0520",

publisher = "Royal Society of Chemistry",

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T1 - Iridium(I) hydroxides in catalysis

T2 - rearrangement of allylic alcohols to ketones

AU - Nelson, David J

AU - Fernández-Salas, José A

AU - Truscott, Byron J

AU - Nolan, Steven P.

PY - 2014

Y1 - 2014

N2 - The iridium(I) hydroxide complex [Ir(OH)(COD)(IiPr)] has been shown to be a competent catalyst for the rearrangement of allylic alcohols to ketones. Reactions proceed in short reaction times (1 − 1.5 h) with microwave heating, in the absence of additives.

AB - The iridium(I) hydroxide complex [Ir(OH)(COD)(IiPr)] has been shown to be a competent catalyst for the rearrangement of allylic alcohols to ketones. Reactions proceed in short reaction times (1 − 1.5 h) with microwave heating, in the absence of additives.

KW - iridium (i)-hydroxide

KW - allylic alcohols

KW - microwave heating

UR - http://pubs.rsc.org/en/journals/journalissues/ob

U2 - 10.1039/C4OB01428F

DO - 10.1039/C4OB01428F

M3 - Article

SN - 1477-0520

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

ER -

Iridium(I) hydroxides in catalysis: rearrangement of allylic alcohols to ketones

Abstract

Keywords

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