Iridium(I) hydroxides in catalysis: rearrangement of allylic alcohols to ketones

David J Nelson, José A Fernández-Salas, Byron J Truscott, Steven P. Nolan

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The iridium(I) hydroxide complex [Ir(OH)(COD)(IiPr)] has been shown to be a competent catalyst for the rearrangement of allylic alcohols to ketones. Reactions proceed in short reaction times (1 − 1.5 h) with microwave heating, in the absence of additives.
LanguageEnglish
JournalOrganic and Biomolecular Chemistry
Early online date15 Jul 2014
DOIs
Publication statusPublished - 2014

Fingerprint

Hydroxides
Iridium
Microwave heating
crack opening displacement
Microwaves
iridium
Ketones
Catalysis
reaction time
ketones
Heating
hydroxides
catalysis
alcohols
microwaves
catalysts
Catalysts
heating
hydroxide ion
allyl alcohol

Keywords

  • iridium (i)-hydroxide
  • allylic alcohols
  • microwave heating

Cite this

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abstract = "The iridium(I) hydroxide complex [Ir(OH)(COD)(IiPr)] has been shown to be a competent catalyst for the rearrangement of allylic alcohols to ketones. Reactions proceed in short reaction times (1 − 1.5 h) with microwave heating, in the absence of additives.",
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Iridium(I) hydroxides in catalysis : rearrangement of allylic alcohols to ketones. / Nelson, David J; Fernández-Salas, José A; Truscott, Byron J; Nolan, Steven P.

In: Organic and Biomolecular Chemistry, 2014.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Iridium(I) hydroxides in catalysis

T2 - Organic and Biomolecular Chemistry

AU - Nelson, David J

AU - Fernández-Salas, José A

AU - Truscott, Byron J

AU - Nolan, Steven P.

PY - 2014

Y1 - 2014

N2 - The iridium(I) hydroxide complex [Ir(OH)(COD)(IiPr)] has been shown to be a competent catalyst for the rearrangement of allylic alcohols to ketones. Reactions proceed in short reaction times (1 − 1.5 h) with microwave heating, in the absence of additives.

AB - The iridium(I) hydroxide complex [Ir(OH)(COD)(IiPr)] has been shown to be a competent catalyst for the rearrangement of allylic alcohols to ketones. Reactions proceed in short reaction times (1 − 1.5 h) with microwave heating, in the absence of additives.

KW - iridium (i)-hydroxide

KW - allylic alcohols

KW - microwave heating

UR - http://pubs.rsc.org/en/journals/journalissues/ob

U2 - 10.1039/C4OB01428F

DO - 10.1039/C4OB01428F

M3 - Article

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

SN - 1477-0520

ER -