Iridium(I) hydroxides in catalysis: rearrangement of allylic alcohols to ketones

David J Nelson, José A Fernández-Salas, Byron J Truscott, Steven P. Nolan

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Abstract

The iridium(I) hydroxide complex [Ir(OH)(COD)(IiPr)] has been shown to be a competent catalyst for the rearrangement of allylic alcohols to ketones. Reactions proceed in short reaction times (1 − 1.5 h) with microwave heating, in the absence of additives.
Original languageEnglish
JournalOrganic and Biomolecular Chemistry
Early online date15 Jul 2014
DOIs
Publication statusPublished - 2014

Keywords

  • iridium (i)-hydroxide
  • allylic alcohols
  • microwave heating

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