Investigation on the valence of Cr ions in LiAlO2

M. Yamaga, J.P.R. Wells, M. Honda, T.P.J. Han, B. Henderson

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The angular dependence of the electron paramagnetic resonance (EPR) spectra of Cr:LiAlO2 does not fit Cr4+ with S=1, but rather Cr3+ with S ¼ 3 2: The energy level (740 cm1) of the first excited state estimated from the temperature dependence of the EPR line width is consistent with the energy separation between two groups of zero-phonon lines in the near-infrared luminescence observed at 10 K. The paramagnetic center observed by the EPR technique is the same as the optically active center. These results suggest the possibility that trivalent chromium ions substitute for trivalent aluminum ions in LiAlO2 with tetrahedral symmetry, without local charge compensators.
Original languageEnglish
Pages (from-to)313-317
Number of pages4
JournalJournal of Luminescence
Volume108
DOIs
Publication statusPublished - Jun 2004

Keywords

  • infrared
  • tunable laser
  • Cr3+
  • oxide crystals
  • LiAlO2
  • lasers
  • nanoscience

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