Investigation of molybdenum-(resorcinol–formaldehyde) (Mo-RF) electrode for alkaline electrolyser operation

Peter Hall

Research output: Contribution to journalArticle

Abstract

The use of zero-gap cell geometry and development of low cost electrodes are some of several attempts on reducing cost and increasing efficiency of electrolytic hydrogen production. This study involves the synthesis of an electrode consisting of resorcinol–formaldehyde (RF) carbon aerogels of high surface area (>700 m2/g) and nano-pore sizes (4 nm) thermally deposited on molybdenum metal. The hydrogen evolution reaction (HER) characteristics of the Mo-RF electrode involving an intermediate ‘spectator metal-oxo’ compound and its Volmer–Heyrovsky electro-catalyst property are described. The physical and morphological structure of the Mo-RF has been shown through SEM images thus confirming the effectiveness of the synthesis method. Polarisation measurement of the Mo-RF electrode in 30% (by vol) KOH solution at 298 K indicates its potential applications in alkaline electrolysers. It is anticipated that the use of Mo-RF electrode offers economic benefit of reduced capital cost investment compared with other electrodes such as Pt–C previously used in electrolysers.
Original languageEnglish
Pages (from-to)7791-7798
Number of pages8
JournalInternational Journal of Hydrogen Energy
Volume36
Issue number13
Early online date3 Mar 2011
DOIs
Publication statusPublished - Jul 2011

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Molybdenum
molybdenum
Electrodes
electrodes
costs
Costs
Aerogels
metal compounds
aerogels
hydrogen production
synthesis
Hydrogen production
Metals
Pore size
economics
Polarization
porosity
catalysts
Hydrogen
Scanning electron microscopy

Keywords

  • hydrogen evolution reaction
  • electrode-catalyst
  • polarisation
  • carbon aerogels
  • volmer–heyrovsky

Cite this

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abstract = "The use of zero-gap cell geometry and development of low cost electrodes are some of several attempts on reducing cost and increasing efficiency of electrolytic hydrogen production. This study involves the synthesis of an electrode consisting of resorcinol–formaldehyde (RF) carbon aerogels of high surface area (>700 m2/g) and nano-pore sizes (4 nm) thermally deposited on molybdenum metal. The hydrogen evolution reaction (HER) characteristics of the Mo-RF electrode involving an intermediate ‘spectator metal-oxo’ compound and its Volmer–Heyrovsky electro-catalyst property are described. The physical and morphological structure of the Mo-RF has been shown through SEM images thus confirming the effectiveness of the synthesis method. Polarisation measurement of the Mo-RF electrode in 30{\%} (by vol) KOH solution at 298 K indicates its potential applications in alkaline electrolysers. It is anticipated that the use of Mo-RF electrode offers economic benefit of reduced capital cost investment compared with other electrodes such as Pt–C previously used in electrolysers.",
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Investigation of molybdenum-(resorcinol–formaldehyde) (Mo-RF) electrode for alkaline electrolyser operation. / Hall, Peter.

In: International Journal of Hydrogen Energy, Vol. 36, No. 13, 07.2011, p. 7791-7798.

Research output: Contribution to journalArticle

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