Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac

A.R. Kennedy; R.E. Mulvey; C.L. Raston; B.A. Roberts; R.B. Rowlings

doi:10.1039/a809681c

Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac

A.R. Kennedy, R.E. Mulvey, C.L. Raston, B.A. Roberts, R.B. Rowlings

Pure And Applied Chemistry

Research output: Contribution to journal › Article

59 Citations (Scopus)

Abstract

The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.

Original language	English
Pages (from-to)	353-354
Number of pages	1
Journal	Chemical Communications (London)
Volume	1999
Issue number	4
DOIs	https://doi.org/10.1039/a809681c
Publication status	Published - 1999

Keywords

potassium
amide-supported heterobimetallic macrocycle
dicationic
octagonal ring

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10.1039/a809681c

http://dx.doi.org/10.1039/a809681c

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Kennedy, A. R., Mulvey, R. E., Raston, C. L., Roberts, B. A., & Rowlings, R. B. (1999). Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac. Chemical Communications (London), 1999(4), 353-354. https://doi.org/10.1039/a809681c

Kennedy, A.R. ; Mulvey, R.E. ; Raston, C.L. ; Roberts, B.A. ; Rowlings, R.B. / Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac. In: Chemical Communications (London). 1999 ; Vol. 1999, No. 4. pp. 353-354.

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abstract = "The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.",

keywords = "potassium, amide-supported heterobimetallic macrocycle, dicationic, octagonal ring",

author = "A.R. Kennedy and R.E. Mulvey and C.L. Raston and B.A. Roberts and R.B. Rowlings",

year = "1999",

doi = "10.1039/a809681c",

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Kennedy, AR , Mulvey, RE, Raston, CL, Roberts, BA & Rowlings, RB 1999, 'Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac', Chemical Communications (London), vol. 1999, no. 4, pp. 353-354. https://doi.org/10.1039/a809681c

Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac. / Kennedy, A.R.; Mulvey, R.E.; Raston, C.L.; Roberts, B.A.; Rowlings, R.B.

In: Chemical Communications (London), Vol. 1999, No. 4, 1999, p. 353-354.

Research output: Contribution to journal › Article

TY - JOUR

T1 - Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac

AU - Kennedy, A.R.

AU - Mulvey, R.E.

AU - Raston, C.L.

AU - Roberts, B.A.

AU - Rowlings, R.B.

PY - 1999

Y1 - 1999

N2 - The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.

AB - The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.

KW - potassium

KW - amide-supported heterobimetallic macrocycle

KW - dicationic

KW - octagonal ring

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U2 - 10.1039/a809681c

DO - 10.1039/a809681c

M3 - Article

VL - 1999

SP - 353

EP - 354

JO - Chemical Communications (London)

JF - Chemical Communications (London)

SN - 0009-241X

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Kennedy AR , Mulvey RE, Raston CL, Roberts BA, Rowlings RB. Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac. Chemical Communications (London). 1999;1999(4):353-354. https://doi.org/10.1039/a809681c