Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac

A.R. Kennedy, R.E. Mulvey, C.L. Raston, B.A. Roberts, R.B. Rowlings

Research output: Contribution to journalArticle

59 Citations (Scopus)

Abstract

The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.
Original languageEnglish
Pages (from-to)353-354
Number of pages1
JournalChemical Communications (London)
Volume1999
Issue number4
DOIs
Publication statusPublished - 1999

Keywords

  • potassium
  • amide-supported heterobimetallic macrocycle
  • dicationic
  • octagonal ring

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