Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac

A.R. Kennedy, R.E. Mulvey, C.L. Raston, B.A. Roberts, R.B. Rowlings

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Abstract

The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.
LanguageEnglish
Pages353-354
Number of pages1
JournalChemical Communications (London)
Volume1999
Issue number4
DOIs
Publication statusPublished - 1999

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Crown Ethers
Amides
Potassium

Keywords

  • potassium
  • amide-supported heterobimetallic macrocycle
  • dicationic
  • octagonal ring

Cite this

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title = "Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac",
abstract = "The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.",
keywords = "potassium, amide-supported heterobimetallic macrocycle, dicationic, octagonal ring",
author = "A.R. Kennedy and R.E. Mulvey and C.L. Raston and B.A. Roberts and R.B. Rowlings",
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volume = "1999",
pages = "353--354",
journal = "Chemical Communications (London)",
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T1 - Inverse crown ether complexes: extension to potassium through the synthesis of [{[(Me3Si)(2)N](4)K2Mg2(O-2)}(infinity)], a peroxo- centred macrocycle linked into infinite chains by intermolecular K center dot center dot center dot CH3(SiMe2) interac

AU - Kennedy, A.R.

AU - Mulvey, R.E.

AU - Raston, C.L.

AU - Roberts, B.A.

AU - Rowlings, R.B.

PY - 1999

Y1 - 1999

N2 - The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.

AB - The title compound represents the first potassium example of a novel class of amide-supported heterobimetallic macrocycle having a dicationic (N4K2Mg2)2+ octagonal ring framework surrounding a dianionic (O2)2- core.

KW - potassium

KW - amide-supported heterobimetallic macrocycle

KW - dicationic

KW - octagonal ring

UR - http://dx.doi.org/10.1039/a809681c

U2 - 10.1039/a809681c

DO - 10.1039/a809681c

M3 - Article

VL - 1999

SP - 353

EP - 354

JO - Chemical Communications (London)

T2 - Chemical Communications (London)

JF - Chemical Communications (London)

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