Increased rate of solvent diffusion in a prototypical supramolecular gel measured on the picosecond timescale

Tilo Seydel; Robert M. Edkins; Christopher D. Jones; Jonathan A. Foster; Robert Bewley; Juan A. Aguilar; Katharina Edkins

doi:10.1039/C8CC02962H

Increased rate of solvent diffusion in a prototypical supramolecular gel measured on the picosecond timescale

Tilo Seydel, Robert M. Edkins, Christopher D. Jones, Jonathan A. Foster, Robert Bewley, Juan A. Aguilar, Katharina Edkins

Research output: Contribution to specialist publication › Article

5 Citations (Scopus)

23 Downloads (Pure)

Abstract

Solvent diffusion in a prototypical supramolecular gel probed by quasi-elastic neutron scattering on the picosecond timescale is faster than that in the respective bulk solvent. This phenomenon is hypothesized to be due to disruption of the hydrogen bonding of the solvent by the large hydrophobic surface of the gel network.

Original language	English
Pages	6340-6343
Number of pages	4
No.	49
Specialist publication	Chemical Communications
DOIs	https://doi.org/10.1039/C8CC02962H
Publication status	Published - 21 Jun 2018

Keywords

solvent diffusion
supramolecular gels
picosecond timescale

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10.1039/C8CC02962H

Seydel-etal-CC-2018-Increased-rate-of-solvent-diffusion-in-a-prototypical-supramolecular-gelAccepted author manuscript, 827 KB

5 Citations
1 Article

Picosecond self-diffusion in ethanol-water mixtures
Seydel, T., Edkins, R. M. & Edkins, K., 16 Apr 2019, In: Physical Chemistry Chemical Physics. 21, 18, p. 9547-9552 6 p.
Research output: Contribution to journal › Article › peer-review

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9 Citations (Scopus)

29 Downloads (Pure)

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title = "Increased rate of solvent diffusion in a prototypical supramolecular gel measured on the picosecond timescale",

abstract = "Solvent diffusion in a prototypical supramolecular gel probed by quasi-elastic neutron scattering on the picosecond timescale is faster than that in the respective bulk solvent. This phenomenon is hypothesized to be due to disruption of the hydrogen bonding of the solvent by the large hydrophobic surface of the gel network.",

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AU - Edkins, Robert M.

AU - Jones, Christopher D.

AU - Foster, Jonathan A.

AU - Bewley, Robert

AU - Aguilar, Juan A.

AU - Edkins, Katharina

PY - 2018/6/21

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AB - Solvent diffusion in a prototypical supramolecular gel probed by quasi-elastic neutron scattering on the picosecond timescale is faster than that in the respective bulk solvent. This phenomenon is hypothesized to be due to disruption of the hydrogen bonding of the solvent by the large hydrophobic surface of the gel network.

KW - solvent diffusion

KW - supramolecular gels

KW - picosecond timescale

U2 - 10.1039/C8CC02962H

DO - 10.1039/C8CC02962H

M3 - Article

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SP - 6340

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JO - Chemical Communications

JF - Chemical Communications

ER -

Increased rate of solvent diffusion in a prototypical supramolecular gel measured on the picosecond timescale

Abstract

Keywords

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Research output

Picosecond self-diffusion in ethanol-water mixtures

Cite this