In situ mapping of electrode potential in a PEM fuel cell

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

Here we describe an innovative fuel cell reference electrode array using a through-plate configuration, which makes possible for the first time accurate mapping of the variation in electrode potential across the active area of an operating polymer electrolyte membrane fuel cell (PEMFC). This configuration overcomes the major limitations of conventional fuel cell reference electrodes in that ohmic drop, potential distribution and electrode edge effects in the membrane are negated. The utility of the technique is neatly demonstrated in the study of catalyst support corrosion during fuel cell start-up, which is associated with movement of the air/fuel boundary through the anode flowfield.

LanguageEnglish
Pages26-29
Number of pages4
JournalElectrochemistry Communications
Volume17
Issue number1
DOIs
Publication statusPublished - Apr 2012

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Fuel cells
Electrodes
Proton exchange membrane fuel cells (PEMFC)
Catalyst supports
Anodes
Corrosion
Membranes
Air

Keywords

  • fuel cell
  • polymer electrolyte membrane
  • reference electrode
  • fuel cell reference electrode array
  • through-plate configuration

Cite this

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In situ mapping of electrode potential in a PEM fuel cell. / Hinds, G.; Brightman, E.

In: Electrochemistry Communications, Vol. 17, No. 1, 04.2012, p. 26-29.

Research output: Contribution to journalArticle

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