Hydrogenated Schiff base ligands: towards the controlled organisation of open metal frameworks

J Reglinski, M K Taylor, A R Kennedy

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

The synthesis and structures of bis-((mu(2)-acetato-O,O')-mu-(N,N'-bis-(o-hydroxybenzyl)-1,3-diaminopropane)-(aquo)nickel)nickel, his((mu(2) -acetato-O,O')-mu-(N,N-bis-(o-hydroxybenzyl)-1,4-diaminobutane nickel)nickel acetate) and bis-((mu(2)-acetato-O,O')-mu-(N,N-bis(o-hydroxybenzyl)-1,4-diaminobutane)-(dimethylformamido)nickel)nickel are reported. These compounds are designed to draw attention to the wider structural catalogue available to symmetrical hydrogenated Schiff base complexes which contain a tetramethylene backbone. (C) 2006 Elsevier B.V. All rights reserved.

LanguageEnglish
Pages736-739
Number of pages4
JournalInorganic Chemistry Communications
Volume9
Issue number7
DOIs
Publication statusPublished - Jul 2006

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Schiff Bases
Nickel
imines
Metals
Ligands
nickel
ligands
Putrescine
metals
catalogs
acetates
synthesis

Keywords

  • tetradentate
  • Schiff base
  • nickel
  • butane-diamine
  • crystal structures
  • complexes
  • geometry

Cite this

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title = "Hydrogenated Schiff base ligands: towards the controlled organisation of open metal frameworks",
abstract = "The synthesis and structures of bis-((mu(2)-acetato-O,O')-mu-(N,N'-bis-(o-hydroxybenzyl)-1,3-diaminopropane)-(aquo)nickel)nickel, his((mu(2) -acetato-O,O')-mu-(N,N-bis-(o-hydroxybenzyl)-1,4-diaminobutane nickel)nickel acetate) and bis-((mu(2)-acetato-O,O')-mu-(N,N-bis(o-hydroxybenzyl)-1,4-diaminobutane)-(dimethylformamido)nickel)nickel are reported. These compounds are designed to draw attention to the wider structural catalogue available to symmetrical hydrogenated Schiff base complexes which contain a tetramethylene backbone. (C) 2006 Elsevier B.V. All rights reserved.",
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}

Hydrogenated Schiff base ligands: towards the controlled organisation of open metal frameworks. / Reglinski, J ; Taylor, M K ; Kennedy, A R .

In: Inorganic Chemistry Communications, Vol. 9, No. 7, 07.2006, p. 736-739.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Hydrogenated Schiff base ligands: towards the controlled organisation of open metal frameworks

AU - Reglinski, J

AU - Taylor, M K

AU - Kennedy, A R

PY - 2006/7

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N2 - The synthesis and structures of bis-((mu(2)-acetato-O,O')-mu-(N,N'-bis-(o-hydroxybenzyl)-1,3-diaminopropane)-(aquo)nickel)nickel, his((mu(2) -acetato-O,O')-mu-(N,N-bis-(o-hydroxybenzyl)-1,4-diaminobutane nickel)nickel acetate) and bis-((mu(2)-acetato-O,O')-mu-(N,N-bis(o-hydroxybenzyl)-1,4-diaminobutane)-(dimethylformamido)nickel)nickel are reported. These compounds are designed to draw attention to the wider structural catalogue available to symmetrical hydrogenated Schiff base complexes which contain a tetramethylene backbone. (C) 2006 Elsevier B.V. All rights reserved.

AB - The synthesis and structures of bis-((mu(2)-acetato-O,O')-mu-(N,N'-bis-(o-hydroxybenzyl)-1,3-diaminopropane)-(aquo)nickel)nickel, his((mu(2) -acetato-O,O')-mu-(N,N-bis-(o-hydroxybenzyl)-1,4-diaminobutane nickel)nickel acetate) and bis-((mu(2)-acetato-O,O')-mu-(N,N-bis(o-hydroxybenzyl)-1,4-diaminobutane)-(dimethylformamido)nickel)nickel are reported. These compounds are designed to draw attention to the wider structural catalogue available to symmetrical hydrogenated Schiff base complexes which contain a tetramethylene backbone. (C) 2006 Elsevier B.V. All rights reserved.

KW - tetradentate

KW - Schiff base

KW - nickel

KW - butane-diamine

KW - crystal structures

KW - complexes

KW - geometry

U2 - 10.1016/j.inoche.2006.04.013

DO - 10.1016/j.inoche.2006.04.013

M3 - Article

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JO - Inorganic Chemistry Communications

T2 - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

SN - 1387-7003

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ER -