Hydrogen isotope exchange with highly active iridium(I) NHC/phosphine complexes: a comparative counter-ion study

William J. Kerr, Richard J. Mudd, Philippa K. Owens, Marc Reid, Jack A. Brown, Sébastien Campos

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12 Citations (Scopus)
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Abstract

Herein we present a range of substrates that undergo hydrogen isotope exchange with an iridium(I) NHC/phosphine complex bearing the less coordinating tetrakis[3,5-bis(trifluoromethyl)phenyl]borate counterion, and compare these with labelling using the equivalent, more established hexafluorophosphate complex. The changes in reactivity and selectivity of these complexes in a series of solvents are examined.
Original languageEnglish
Pages (from-to)601-603
Number of pages4
JournalJournal of Labelled Compounds and Radiopharmaceuticals
Volume59
Issue number14
Early online date27 Jul 2016
DOIs
Publication statusPublished - 31 Dec 2016

Keywords

  • ortho-hydrogen isotope exchange
  • N-heterocyclic carbene
  • deuteration
  • iridium

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