Hydrogen adsorption on graphene foam synthesized by combustion of sodium ethoxide

Stephen Matthew Lyth*, Huaiyu Shao, Jianfeng Liu, Kazunari Sasaki, Etsuo Akiba

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

39 Citations (Scopus)

Abstract

Hydrogen storage is a crucial technology for the realization of a carbon-neutral society. However, few materials have been able to approach useful hydrogen storage capacity at reasonable temperatures and pressures. Graphene has an extremely high surface-area-to-weight ratio, is strong, cheap, chemically inert, and environmentally benign. As such it may be an ideal substrate for hydrogen storage. Here we present synthesis of graphene foam by combustion of sodium ethoxide. This technique is low-cost, scalable, and results in a three-dimensional graphene network with a surface area of more than 1200 m 2/g. It is applied as a hydrogen storage material at liquid nitrogen temperature, with a capacity of 2.1 wt%.

Original languageEnglish
Pages (from-to)376-380
Number of pages5
JournalInternational Journal of Hydrogen Energy
Volume39
Issue number1
DOIs
Publication statusPublished - 2 Jan 2014

Funding

The author(s) gratefully acknowledge the support of the International Institute for Carbon Neutral Energy Research (WPI-I2CNER), sponsored by the World Premier International Research Center Initiative (WPI), MEXT, Japan .

Keywords

  • graphene
  • hydrogen
  • sorption
  • storage
  • synthesis

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