Hydride encapsulation in s-block metal inverse crown chemistry

D.J. Gallagher, K.W. Henderson, A.R. Kennedy, C.T. O'Hara, R.E. Mulvey, R.B. Rowlings

Research output: Contribution to journalArticle

73 Citations (Scopus)

Abstract

A new category of 'inverse crown' complex has been established through the synthesis of the disodium-dimagnesium diisopropylamide [Na2Mg2{N(Pr-i)(2)}(4)(mu-H)(2).(toluene)(2)], the first such complex to exhibit hydride encapsulation, a non-planar octagonal 'host' ring or solvent stabilisation.
Original languageEnglish
Pages (from-to)376-377
Number of pages1
JournalChemical Communications (London)
Volume2002
Issue number4
DOIs
Publication statusPublished - 2002

Keywords

  • REDUCTION
  • COMPLEXES
  • KETONES

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