Hydride encapsulation in s-block metal inverse crown chemistry

D.J. Gallagher, K.W. Henderson, A.R. Kennedy, C.T. O'Hara, R.E. Mulvey, R.B. Rowlings

Research output: Contribution to journalArticle

71 Citations (Scopus)

Abstract

A new category of 'inverse crown' complex has been established through the synthesis of the disodium-dimagnesium diisopropylamide [Na2Mg2{N(Pr-i)(2)}(4)(mu-H)(2).(toluene)(2)], the first such complex to exhibit hydride encapsulation, a non-planar octagonal 'host' ring or solvent stabilisation.
Original languageEnglish
Pages (from-to)376-377
Number of pages1
JournalChemical Communications (London)
Volume2002
Issue number4
DOIs
Publication statusPublished - 2002

Fingerprint

Toluene
Encapsulation
Hydrides
Stabilization
Metals

Keywords

  • REDUCTION
  • COMPLEXES
  • KETONES

Cite this

Gallagher, D.J. ; Henderson, K.W. ; Kennedy, A.R. ; O'Hara, C.T. ; Mulvey, R.E. ; Rowlings, R.B. / Hydride encapsulation in s-block metal inverse crown chemistry. In: Chemical Communications (London). 2002 ; Vol. 2002, No. 4. pp. 376-377.
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Hydride encapsulation in s-block metal inverse crown chemistry. / Gallagher, D.J.; Henderson, K.W.; Kennedy, A.R.; O'Hara, C.T.; Mulvey, R.E.; Rowlings, R.B.

In: Chemical Communications (London), Vol. 2002, No. 4, 2002, p. 376-377.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Hydride encapsulation in s-block metal inverse crown chemistry

AU - Gallagher, D.J.

AU - Henderson, K.W.

AU - Kennedy, A.R.

AU - O'Hara, C.T.

AU - Mulvey, R.E.

AU - Rowlings, R.B.

PY - 2002

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KW - REDUCTION

KW - COMPLEXES

KW - KETONES

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DO - 10.1039/b110117j

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EP - 377

JO - Chemical Communications (London)

JF - Chemical Communications (London)

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