Hydride encapsulation in s-block metal inverse crown chemistry

D.J. Gallagher; K.W. Henderson; A.R. Kennedy; C.T. O'Hara; R.E. Mulvey; R.B. Rowlings

doi:10.1039/b110117j

Hydride encapsulation in s-block metal inverse crown chemistry

D.J. Gallagher, K.W. Henderson, A.R. Kennedy, C.T. O'Hara, R.E. Mulvey, R.B. Rowlings

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

85 Citations (Scopus)

Abstract

A new category of 'inverse crown' complex has been established through the synthesis of the disodium-dimagnesium diisopropylamide [Na2Mg2{N(Pr-i)(2)}(4)(mu-H)(2).(toluene)(2)], the first such complex to exhibit hydride encapsulation, a non-planar octagonal 'host' ring or solvent stabilisation.

Original language	English
Pages (from-to)	376-377
Number of pages	1
Journal	Chemical Communications (London)
Volume	2002
Issue number	4
DOIs	https://doi.org/10.1039/b110117j
Publication status	Published - 2002

Keywords

REDUCTION
COMPLEXES
KETONES

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10.1039/b110117j

Cite this

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title = "Hydride encapsulation in s-block metal inverse crown chemistry",

abstract = "A new category of 'inverse crown' complex has been established through the synthesis of the disodium-dimagnesium diisopropylamide [Na2Mg2{N(Pr-i)(2)}(4)(mu-H)(2).(toluene)(2)], the first such complex to exhibit hydride encapsulation, a non-planar octagonal 'host' ring or solvent stabilisation.",

keywords = "REDUCTION, COMPLEXES, KETONES",

author = "D.J. Gallagher and K.W. Henderson and A.R. Kennedy and C.T. O'Hara and R.E. Mulvey and R.B. Rowlings",

year = "2002",

doi = "10.1039/b110117j",

language = "English",

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journal = "Chemical Communications (London)",

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T1 - Hydride encapsulation in s-block metal inverse crown chemistry

AU - Gallagher, D.J.

AU - Henderson, K.W.

AU - Kennedy, A.R.

AU - O'Hara, C.T.

AU - Mulvey, R.E.

AU - Rowlings, R.B.

PY - 2002

Y1 - 2002

N2 - A new category of 'inverse crown' complex has been established through the synthesis of the disodium-dimagnesium diisopropylamide [Na2Mg2{N(Pr-i)(2)}(4)(mu-H)(2).(toluene)(2)], the first such complex to exhibit hydride encapsulation, a non-planar octagonal 'host' ring or solvent stabilisation.

AB - A new category of 'inverse crown' complex has been established through the synthesis of the disodium-dimagnesium diisopropylamide [Na2Mg2{N(Pr-i)(2)}(4)(mu-H)(2).(toluene)(2)], the first such complex to exhibit hydride encapsulation, a non-planar octagonal 'host' ring or solvent stabilisation.

KW - REDUCTION

KW - COMPLEXES

KW - KETONES

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UR - http://dx.doi.org/10.1039/b110117j

U2 - 10.1039/b110117j

DO - 10.1039/b110117j

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SP - 376

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JO - Chemical Communications (London)

JF - Chemical Communications (London)

SN - 0009-241X

IS - 4

ER -

Hydride encapsulation in s-block metal inverse crown chemistry

Abstract

Keywords

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Hydride encapsulation in s-block metal inverse crown chemistry

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