Homoleptic crown n-heterocyclic carbene complexes

Ross McKie, J.A. Murphy, S.R. Park, M.D. Spicer, S. Zhou

Research output: Contribution to journalArticle

91 Citations (Scopus)

Abstract

The first metal N-heterocyclic carbene complexes derived from a cyclic tetraimidazolium salt show a remarkable versatility of ligand conformation and coordination geometry. With PdII, a mononuclear square-planar complex is obtained, but with CuI and AgI, an unprecedented dinuclear motif with a short metal–metal interaction is observed (see structure; N blue, C white ellipsoids, H white circles).
Original languageEnglish
Pages (from-to)6525-6528
Number of pages4
JournalAgewandte Chemie-International Edition
Volume46
Issue number34
Early online date23 Jul 2007
DOIs
Publication statusPublished - 27 Aug 2007

Keywords

  • carbene ligands
  • copper
  • macrocyclic ligands
  • palladium
  • silver

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