@article{d23d9f06523d4365b9162db8e8e5f12b,
title = "Heavier alkali-metal gallates as platforms for accessing functionalized abnormal NHC carbene-gallium complexes",
abstract = "By sequentially treating the unsaturated carbene IPr (IPr = 1,3-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene) with heavier alkali-metal alkyls NaR or KR (R = CH2SiMe3) and GaR3, novel heteroleptic gallates 1 and 2 have been prepared. Incorporating anionic NHC ligands, these bimetallic complexes react selectively with electrophilles to afford neutral abnormal NHC Ga complexes under mild conditions. ",
keywords = "gallium, sodium, potassium, carbene ligands, coordination chemistry, N-heterocyclic carbenes, metallating ability, alkali-metal alkyls",
author = "Marina Uzelac and Kennedy, {Alan R.} and Alberto Hern{\'a}n-G{\'o}mez and Fuentes, {M. {\'A}ngeles} and Eva Hevia",
note = "This is the peer reviewed version of the following article: Uzelac, M., Kennedy, A. R., Hern{\'a}n-G{\'o}mez, A., Fuentes, M. {\'A}., & Hevia, E. (2016). Heavier alkali-metal gallates as platforms for accessing functionalized abnormal NHC carbene-gallium complexes. Zeitschrift fur Anorganische und Allgemeine Chemie, 642(22), 1241-1244, which has been published in final form at https://dx.doi.org/10.1002/zaac.201600310. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving",
year = "2016",
month = nov,
day = "16",
doi = "10.1002/zaac.201600310",
language = "English",
volume = "642",
pages = "1241--1244",
journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",
issn = "0044-2313",
publisher = "Wiley-VCH Verlag",
number = "22",
}