From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis

Simone Manzini, David J. Nelson, Tomas Lebl, Albert Poater, Luigi Cavallo, Alexandra M Z Slawin, Steven P. Nolan

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The synthesis and characterisation of [Ru(H)(η5-3- phenylindenyl)(iBu-Phoban)2] 4 is reported ( iBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst M11, in a process that was previously thought to be limited to analogous complex [RuCl 2(PPh3)2(3-phenylindenylidene)] (M 10).

Original languageEnglish
Pages (from-to)2205-2207
Number of pages3
JournalChemical Communications
Volume50
Issue number17
Early online date10 Jan 2014
DOIs
Publication statusPublished - 28 Feb 2014
Externally publishedYes

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Ruthenium
Alkenes
Olefins
Catalysts
nonane

Keywords

  • ruthenium olefin
  • alcoholysis
  • metathesis

Cite this

Manzini, Simone ; Nelson, David J. ; Lebl, Tomas ; Poater, Albert ; Cavallo, Luigi ; Slawin, Alexandra M Z ; Nolan, Steven P. / From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis. In: Chemical Communications. 2014 ; Vol. 50, No. 17. pp. 2205-2207.
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Manzini, S, Nelson, DJ, Lebl, T, Poater, A, Cavallo, L, Slawin, AMZ & Nolan, SP 2014, 'From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis', Chemical Communications, vol. 50, no. 17, pp. 2205-2207. https://doi.org/10.1039/c3cc49481k

From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis. / Manzini, Simone; Nelson, David J.; Lebl, Tomas; Poater, Albert; Cavallo, Luigi; Slawin, Alexandra M Z; Nolan, Steven P.

In: Chemical Communications, Vol. 50, No. 17, 28.02.2014, p. 2205-2207.

Research output: Contribution to journalArticle

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T1 - From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis

AU - Manzini, Simone

AU - Nelson, David J.

AU - Lebl, Tomas

AU - Poater, Albert

AU - Cavallo, Luigi

AU - Slawin, Alexandra M Z

AU - Nolan, Steven P.

PY - 2014/2/28

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