From ruthenium olefin metathesis catalyst to (η5-3- phenylindenyl)hydrido complex via alcoholysis

Simone Manzini, David J. Nelson, Tomas Lebl, Albert Poater, Luigi Cavallo, Alexandra M Z Slawin, Steven P. Nolan

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The synthesis and characterisation of [Ru(H)(η5-3- phenylindenyl)(iBu-Phoban)2] 4 is reported ( iBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst M11, in a process that was previously thought to be limited to analogous complex [RuCl 2(PPh3)2(3-phenylindenylidene)] (M 10).

Original languageEnglish
Pages (from-to)2205-2207
Number of pages3
JournalChemical Communications
Volume50
Issue number17
Early online date10 Jan 2014
DOIs
Publication statusPublished - 28 Feb 2014
Externally publishedYes

Keywords

  • ruthenium olefin
  • alcoholysis
  • metathesis

Fingerprint Dive into the research topics of 'From ruthenium olefin metathesis catalyst to (η<sup>5</sup>-3- phenylindenyl)hydrido complex via alcoholysis'. Together they form a unique fingerprint.

  • Cite this