Freezing properties of alkenyl succinic anhydrides derived from linear isomerised olefins

Philip B. Sellars; Leo Lue; Iain S. Burns; D. Neil Work

doi:10.1021/acs.iecr.5b04769

Freezing properties of alkenyl succinic anhydrides derived from linear isomerised olefins

Philip B. Sellars, Leo Lue, Iain S. Burns, D. Neil Work

Chemical And Process Engineering

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Abstract

Alkenyl succinic anhydrides are important specialty chemicals that are used in the paper, oilfield and fuel additives industries. In this paper we investigate the link between the physical properties of alkenyl succinic anhydrides and the identities of their linear alkyl olefin precursors. We describe a straightforward GC analysis of olefin isomer distributions and show that these correlate well with the freezing temperatures of the subsequent alkenyl succinic anhydride products. This allows the identification of olefin isomer profiles that are required to give the desired physical properties in the alkenyl succinic anhydrides; it also provides a method to predict the freezing temperatures of alkenyl succinic anhydrides synthesised from a particular supply of olefin.

Original language	English
Pages (from-to)	2287–2292
Number of pages	6
Journal	Industrial and Engineering Chemistry Research
Volume	55
Issue number	8
Early online date	8 Feb 2016
DOIs	https://doi.org/10.1021/acs.iecr.5b04769
Publication status	Published - 8 Feb 2016

Keywords

alkenyl succinic anhydrides
speciality chemicals
alkyl olefin precursors
GC analysis
olefin isomer profiles

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10.1021/acs.iecr.5b04769

Sellars-etal-IECR2016-freezing-properties-of-alkenyl-succinic-anhydrides-derived-from-linear-isomerised-olefinsAccepted author manuscript, 539 KB

KTP - Pentagon Chemicals
Lue, L. & Burns, I.
KTP Govt (TSB), Pentagon Chemical Specialities Limited
25/11/13 → 24/11/15
Project: Research

Cite this

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title = "Freezing properties of alkenyl succinic anhydrides derived from linear isomerised olefins",

abstract = "Alkenyl succinic anhydrides are important specialty chemicals that are used in the paper, oilfield and fuel additives industries. In this paper we investigate the link between the physical properties of alkenyl succinic anhydrides and the identities of their linear alkyl olefin precursors. We describe a straightforward GC analysis of olefin isomer distributions and show that these correlate well with the freezing temperatures of the subsequent alkenyl succinic anhydride products. This allows the identification of olefin isomer profiles that are required to give the desired physical properties in the alkenyl succinic anhydrides; it also provides a method to predict the freezing temperatures of alkenyl succinic anhydrides synthesised from a particular supply of olefin.",

keywords = "alkenyl succinic anhydrides, speciality chemicals, alkyl olefin precursors, GC analysis, olefin isomer profiles",

author = "Sellars, {Philip B.} and Leo Lue and Burns, {Iain S.} and Work, {D. Neil}",

note = "This document is the Accepted Manuscript version of a Published Work that appeared in final form in Industrial and Engineering Chemistry Research, copyright {\textcopyright} American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.iecr.5b04769",

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journal = "Industrial and Engineering Chemistry Research",

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AU - Sellars, Philip B.

AU - Lue, Leo

AU - Burns, Iain S.

AU - Work, D. Neil

N1 - This document is the Accepted Manuscript version of a Published Work that appeared in final form in Industrial and Engineering Chemistry Research, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acs.iecr.5b04769

PY - 2016/2/8

Y1 - 2016/2/8

N2 - Alkenyl succinic anhydrides are important specialty chemicals that are used in the paper, oilfield and fuel additives industries. In this paper we investigate the link between the physical properties of alkenyl succinic anhydrides and the identities of their linear alkyl olefin precursors. We describe a straightforward GC analysis of olefin isomer distributions and show that these correlate well with the freezing temperatures of the subsequent alkenyl succinic anhydride products. This allows the identification of olefin isomer profiles that are required to give the desired physical properties in the alkenyl succinic anhydrides; it also provides a method to predict the freezing temperatures of alkenyl succinic anhydrides synthesised from a particular supply of olefin.

AB - Alkenyl succinic anhydrides are important specialty chemicals that are used in the paper, oilfield and fuel additives industries. In this paper we investigate the link between the physical properties of alkenyl succinic anhydrides and the identities of their linear alkyl olefin precursors. We describe a straightforward GC analysis of olefin isomer distributions and show that these correlate well with the freezing temperatures of the subsequent alkenyl succinic anhydride products. This allows the identification of olefin isomer profiles that are required to give the desired physical properties in the alkenyl succinic anhydrides; it also provides a method to predict the freezing temperatures of alkenyl succinic anhydrides synthesised from a particular supply of olefin.

KW - alkenyl succinic anhydrides

KW - speciality chemicals

KW - alkyl olefin precursors

KW - GC analysis

KW - olefin isomer profiles

U2 - 10.1021/acs.iecr.5b04769

DO - 10.1021/acs.iecr.5b04769

M3 - Article

SN - 0888-5885

VL - 55

SP - 2287

EP - 2292

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 8

ER -

Freezing properties of alkenyl succinic anhydrides derived from linear isomerised olefins

Abstract

Keywords

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KTP - Pentagon Chemicals

Cite this