Formation of the lithium alkylaluminium secondary amide [Me2Al{PhCH2}2Li.THF] by a methane elimination / amide insertion process

D.R. Armstrong; F.J. Craig; A.R. Kennedy; R.E. Mulvey

doi:10.1016/S0022-328X(97)00549-4

Formation of the lithium alkylaluminium secondary amide [Me2Al{PhCH2}2Li.THF] by a methane elimination / amide insertion process

D.R. Armstrong, F.J. Craig, A.R. Kennedy, R.E. Mulvey

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Synthesised by refluxing the amine adduct [Me3Al · (PhCH2)2NLi · HN(CH2Ph)2] in toluene/THF, the title compound has been structurally characterised by X-ray diffraction, and the methane elimination/amide insertion processes involved in its formation have been modelled theoretically through a series of ab initio MO calculations.

Original language	English
Pages (from-to)	355-358
Number of pages	3
Journal	Journal of Organometallic Chemistry
Volume	550
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(97)00549-4
Publication status	Published - 27 Apr 1998

Keywords

Ab initio
X-ray diffraction
Heterobimetallics
Aluminium
Amide
Lithium

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10.1016/S0022-328X(97)00549-4

x-ray diffractometer
Kennedy, A.
Pure And Applied Chemistry
Facility/equipment: Equipment

Cite this

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title = "Formation of the lithium alkylaluminium secondary amide [Me2Al\{PhCH2\}2Li.THF] by a methane elimination / amide insertion process",

abstract = "Synthesised by refluxing the amine adduct [Me3Al · (PhCH2)2NLi · HN(CH2Ph)2] in toluene/THF, the title compound has been structurally characterised by X-ray diffraction, and the methane elimination/amide insertion processes involved in its formation have been modelled theoretically through a series of ab initio MO calculations.",

keywords = "Ab initio, X-ray diffraction, Heterobimetallics, Aluminium, Amide, Lithium",

author = "D.R. Armstrong and F.J. Craig and A.R. Kennedy and R.E. Mulvey",

year = "1998",

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doi = "10.1016/S0022-328X(97)00549-4",

language = "English",

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TY - JOUR

T1 - Formation of the lithium alkylaluminium secondary amide [Me2Al{PhCH2}2Li.THF] by a methane elimination / amide insertion process

AU - Armstrong, D.R.

AU - Craig, F.J.

AU - Kennedy, A.R.

AU - Mulvey, R.E.

PY - 1998/4/27

Y1 - 1998/4/27

N2 - Synthesised by refluxing the amine adduct [Me3Al · (PhCH2)2NLi · HN(CH2Ph)2] in toluene/THF, the title compound has been structurally characterised by X-ray diffraction, and the methane elimination/amide insertion processes involved in its formation have been modelled theoretically through a series of ab initio MO calculations.

AB - Synthesised by refluxing the amine adduct [Me3Al · (PhCH2)2NLi · HN(CH2Ph)2] in toluene/THF, the title compound has been structurally characterised by X-ray diffraction, and the methane elimination/amide insertion processes involved in its formation have been modelled theoretically through a series of ab initio MO calculations.

KW - Ab initio

KW - X-ray diffraction

KW - Heterobimetallics

KW - Aluminium

KW - Amide

KW - Lithium

U2 - 10.1016/S0022-328X(97)00549-4

DO - 10.1016/S0022-328X(97)00549-4

M3 - Article

SN - 0022-328X

VL - 550

SP - 355

EP - 358

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Formation of the lithium alkylaluminium secondary amide [Me2Al{PhCH2}2Li.THF] by a methane elimination / amide insertion process

Abstract

Keywords

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Equipment

x-ray diffractometer

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