Abstract
Synthesised by refluxing the amine adduct [Me3Al · (PhCH2)2NLi · HN(CH2Ph)2] in toluene/THF, the title compound has been structurally characterised by X-ray diffraction, and the methane elimination/amide insertion processes involved in its formation have been modelled theoretically through a series of ab initio MO calculations.
Original language | English |
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Pages (from-to) | 355-358 |
Number of pages | 3 |
Journal | Journal of Organometallic Chemistry |
Volume | 550 |
Issue number | 1-2 |
DOIs | |
Publication status | Published - 27 Apr 1998 |
Keywords
- Ab initio
- X-ray diffraction
- Heterobimetallics
- Aluminium
- Amide
- Lithium