Ferrocene derivatives. 27. Ferrocenyldimethylphosphine

Graham R. Knox; Peter L. Pauson; Debra Willison

doi:10.1021/om00044a038

Ferrocene derivatives. 27. Ferrocenyldimethylphosphine

Graham R. Knox, Peter L. Pauson, Debra Willison

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

An improved synthesis of ferrocenyldimethlphophine, FcPMe2, is limited only by the unreliable literature procedure for preparing precursor dichloroferrocenylphosphine, FcPCl2. The latter compound yields a crystalline copper(I) iodide complex on reaction with lithium dimethlcuprate. Methanolysis of FCPCl2 yields unstable dimethl ferrocenylphosphonite, FcP(OMe)2, which is converted to methyl ferrocenylphosphinite, FcPH(O)OMe, on heating or chromatography.

Original language	English
Pages (from-to)	2930-2933
Number of pages	4
Journal	Organometallics
Volume	11
Issue number	8
DOIs	https://doi.org/10.1021/om00044a038
Publication status	Published - 1 Aug 1992

Keywords

ferrocenyldimethlphosphine
copper iodide
chromatography

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10.1021/om00044a038

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title = "Ferrocene derivatives. 27. Ferrocenyldimethylphosphine",

abstract = "An improved synthesis of ferrocenyldimethlphophine, FcPMe2, is limited only by the unreliable literature procedure for preparing precursor dichloroferrocenylphosphine, FcPCl2. The latter compound yields a crystalline copper(I) iodide complex on reaction with lithium dimethlcuprate. Methanolysis of FCPCl2 yields unstable dimethl ferrocenylphosphonite, FcP(OMe)2, which is converted to methyl ferrocenylphosphinite, FcPH(O)OMe, on heating or chromatography.",

keywords = "ferrocenyldimethlphosphine, copper iodide, chromatography",

author = "Knox, {Graham R.} and Pauson, {Peter L.} and Debra Willison",

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doi = "10.1021/om00044a038",

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journal = "Organometallics",

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T1 - Ferrocene derivatives. 27. Ferrocenyldimethylphosphine

AU - Knox, Graham R.

AU - Pauson, Peter L.

AU - Willison, Debra

PY - 1992/8/1

Y1 - 1992/8/1

N2 - An improved synthesis of ferrocenyldimethlphophine, FcPMe2, is limited only by the unreliable literature procedure for preparing precursor dichloroferrocenylphosphine, FcPCl2. The latter compound yields a crystalline copper(I) iodide complex on reaction with lithium dimethlcuprate. Methanolysis of FCPCl2 yields unstable dimethl ferrocenylphosphonite, FcP(OMe)2, which is converted to methyl ferrocenylphosphinite, FcPH(O)OMe, on heating or chromatography.

AB - An improved synthesis of ferrocenyldimethlphophine, FcPMe2, is limited only by the unreliable literature procedure for preparing precursor dichloroferrocenylphosphine, FcPCl2. The latter compound yields a crystalline copper(I) iodide complex on reaction with lithium dimethlcuprate. Methanolysis of FCPCl2 yields unstable dimethl ferrocenylphosphonite, FcP(OMe)2, which is converted to methyl ferrocenylphosphinite, FcPH(O)OMe, on heating or chromatography.

KW - ferrocenyldimethlphosphine

KW - copper iodide

KW - chromatography

U2 - 10.1021/om00044a038

DO - 10.1021/om00044a038

M3 - Article

SN - 0276-7333

VL - 11

SP - 2930

EP - 2933

JO - Organometallics

JF - Organometallics

IS - 8

ER -

Ferrocene derivatives. 27. Ferrocenyldimethylphosphine

Abstract

Keywords

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