Abstract
| Language | English |
|---|---|
| Pages | 5452-5455 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 51 |
| Issue number | 25 |
| Early online date | 10 Sep 2014 |
| DOIs | |
| Publication status | Published - 28 Mar 2015 |
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Keywords
- crystallography
- isomers
- hexane solubility
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Facile synthesis of a genuinely alkane-soluble but isolable lithium hydride transfer reagent. / Robertson, Stuart D.; Kennedy, Alan R.; Liggat, John J.; Mulvey, Robert E.
In: Chemical Communications, Vol. 51, No. 25, 28.03.2015, p. 5452-5455.Research output: Contribution to journal › Article
TY - JOUR
T1 - Facile synthesis of a genuinely alkane-soluble but isolable lithium hydride transfer reagent
AU - Robertson, Stuart D.
AU - Kennedy, Alan R.
AU - Liggat, John J.
AU - Mulvey, Robert E.
PY - 2015/3/28
Y1 - 2015/3/28
N2 - 1-lithio-2-butyl-1,2-dihydropyridines, typically formed as intermediates in the nucleophilic substitution (addition/elimination) of pyridine with (n- or t-) butyl lithium, have been isolated and comprehensively characterized. The linear substituted isomer is polymeric while the branched substituted isomer is a cyclotrimer. The lower oligomerization of the latter complex confers exceptional hexane solubility making it an excellent lithium hydride source in non-polar, aliphatic media.
AB - 1-lithio-2-butyl-1,2-dihydropyridines, typically formed as intermediates in the nucleophilic substitution (addition/elimination) of pyridine with (n- or t-) butyl lithium, have been isolated and comprehensively characterized. The linear substituted isomer is polymeric while the branched substituted isomer is a cyclotrimer. The lower oligomerization of the latter complex confers exceptional hexane solubility making it an excellent lithium hydride source in non-polar, aliphatic media.
KW - crystallography
KW - isomers
KW - hexane solubility
UR - http://www.scopus.com/inward/record.url?scp=84925060810&partnerID=8YFLogxK
UR - http://pubs.rsc.org/en/journals/journalissues/cc
U2 - 10.1039/C4CC06421F
DO - 10.1039/C4CC06421F
M3 - Article
VL - 51
SP - 5452
EP - 5455
JO - Chemical Communications
T2 - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 25
ER -