TY - JOUR
T1 - Facile designing and assessment of photovoltaic performance of hydrothermally grown kesterite Cu2ZnSnS4 thin films
T2 - influence of deposition time
AU - Patil, Satish S.
AU - Mane, Rahul M.
AU - Mali, Sawanta S.
AU - Hong, Chang K.
AU - Bhosale, Popatrao N.
PY - 2020/5/1
Y1 - 2020/5/1
N2 - Herein, low cost precursor source Cu2ZnSnS4 (CZTS) nanocrystalline thin films at various reaction time were successfully synthesized via one step hydrothermal route. Hydrothermal route was employed to achieve control over the size and grain growth of CZTS films. As deposited CZTS films were analyzed for its optoelectronic, structural, morphological and electrochemical properties to investigate the effect of hydrothermal reaction time on growth and photovoltaic performance. The hydrothermal synthesis promoted to high absorption (104 cm−1) of the CZTS film with a decrease in optical band gap energy from 1.52 eV to 1.41 eV. Structural study revealed that, improved crystallinity with A1 mode of vibration for pure phase kesterite CZTS structure. Morphological transition was observed from nanograins to well grown and compact nanospheres. Compositional analysis illustrates, stoichiometric CZTS film formation with the desired valence state of Cu+, Zn2+, Sn4+ and S2− elements. Current density-voltage (J-V) measurement of FTO/CZTS/(0.3 M Eu3+/Eu2+)/Graphite cell configuration shows, highest photocurrent of 2.60 mA/cm2 and open circuit voltage of 754 mV was observed for CZTS4 sample with best photoconversion efficiency (η) 3.21% under illumination of 30 mW/cm2 light intensity. Electron impedance spectroscopy (EIS) showed that, generation of lower charge transfer resistance (Rct) with increase in reaction time.
AB - Herein, low cost precursor source Cu2ZnSnS4 (CZTS) nanocrystalline thin films at various reaction time were successfully synthesized via one step hydrothermal route. Hydrothermal route was employed to achieve control over the size and grain growth of CZTS films. As deposited CZTS films were analyzed for its optoelectronic, structural, morphological and electrochemical properties to investigate the effect of hydrothermal reaction time on growth and photovoltaic performance. The hydrothermal synthesis promoted to high absorption (104 cm−1) of the CZTS film with a decrease in optical band gap energy from 1.52 eV to 1.41 eV. Structural study revealed that, improved crystallinity with A1 mode of vibration for pure phase kesterite CZTS structure. Morphological transition was observed from nanograins to well grown and compact nanospheres. Compositional analysis illustrates, stoichiometric CZTS film formation with the desired valence state of Cu+, Zn2+, Sn4+ and S2− elements. Current density-voltage (J-V) measurement of FTO/CZTS/(0.3 M Eu3+/Eu2+)/Graphite cell configuration shows, highest photocurrent of 2.60 mA/cm2 and open circuit voltage of 754 mV was observed for CZTS4 sample with best photoconversion efficiency (η) 3.21% under illumination of 30 mW/cm2 light intensity. Electron impedance spectroscopy (EIS) showed that, generation of lower charge transfer resistance (Rct) with increase in reaction time.
KW - Cu2ZnSnS4 thin films
KW - electron impedance spectroscopy
KW - hydrothermal route
KW - photoelectrochemical (PEC) cell
U2 - 10.1016/j.solener.2020.02.089
DO - 10.1016/j.solener.2020.02.089
M3 - Article
AN - SCOPUS:85080896237
SN - 0038-092X
VL - 201
SP - 102
EP - 115
JO - Solar Energy
JF - Solar Energy
ER -
