Exploring the coordination of cyclic selenoureas to gold(I)

David J Nelson; Fady Nahra; Scott R Patrick; David B Cordes; Alexandra M. Z. Slawin; Steven P Nolan

doi:10.1021/om500610w

Exploring the coordination of cyclic selenoureas to gold(I)

David J Nelson, Fady Nahra, Scott R Patrick, David B Cordes, Alexandra M. Z. Slawin, Steven P Nolan

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

81 Citations (Scopus)

Abstract

NHC-derived selenoureas, which are useful for the quantification of NHC electronic properties, are deployed as ligands for Au(I). Surprisingly, while some compounds led to the expected [AuCl(SeUr)] species, selenoureas derived from more π-
accepting NHCs unexpectedly furnished crystals of the corresponding [Au(SeUr)2][AuCl2] species in which ligand rearrangement had occurred

Original language	English
Pages (from-to)	3640-3645
Number of pages	6
Journal	Organometallics
Volume	33
Issue number	13
Early online date	2 Jul 2014
DOIs	https://doi.org/10.1021/om500610w
Publication status	Published - 2014

Keywords

N-heterocyclic carbenes
gold(I)
co-ordination chemistry
selenium, ligands

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10.1021/om500610w

Coinage metal complexes of selenoureas derived from N-heterocyclic carbenes
Nelson, D. (Creator) & Nahra, F. (Creator), University of Strathclyde, 30 May 2018
DOI: 10.15129/4d2063a1-9c41-44ee-ac7f-7a4fab130852
Dataset

81 Citations
1 Article

Straightforward access to chalcogenoureas derived from N-heterocyclic carbenes and their coordination chemistry
Saab, M., Nelson, D. J., Tzouras, N. V., Bayrakdar, T. A. C. A., Nolan, S. P., Nahra, F. & van Hecke, K., 14 Sept 2020, In: Dalton Transactions. 49, 34, p. 12068-12081 14 p.
Research output: Contribution to journal › Article › peer-review

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28 Citations (Scopus)

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title = "Exploring the coordination of cyclic selenoureas to gold(I)",

abstract = "NHC-derived selenoureas, which are useful for the quantification of NHC electronic properties, are deployed as ligands for Au(I). Surprisingly, while some compounds led to the expected [AuCl(SeUr)] species, selenoureas derived from more π-accepting NHCs unexpectedly furnished crystals of the corresponding [Au(SeUr)2][AuCl2] species in which ligand rearrangement had occurred",

keywords = "N-heterocyclic carbenes, gold(I), co-ordination chemistry, selenium, ligands",

author = "Nelson, {David J} and Fady Nahra and Patrick, {Scott R} and Cordes, {David B} and Slawin, {Alexandra M. Z.} and Nolan, {Steven P}",

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AU - Nelson, David J

AU - Nahra, Fady

AU - Patrick, Scott R

AU - Cordes, David B

AU - Slawin, Alexandra M. Z.

AU - Nolan, Steven P

PY - 2014

Y1 - 2014

N2 - NHC-derived selenoureas, which are useful for the quantification of NHC electronic properties, are deployed as ligands for Au(I). Surprisingly, while some compounds led to the expected [AuCl(SeUr)] species, selenoureas derived from more π-accepting NHCs unexpectedly furnished crystals of the corresponding [Au(SeUr)2][AuCl2] species in which ligand rearrangement had occurred

AB - NHC-derived selenoureas, which are useful for the quantification of NHC electronic properties, are deployed as ligands for Au(I). Surprisingly, while some compounds led to the expected [AuCl(SeUr)] species, selenoureas derived from more π-accepting NHCs unexpectedly furnished crystals of the corresponding [Au(SeUr)2][AuCl2] species in which ligand rearrangement had occurred

KW - N-heterocyclic carbenes

KW - gold(I)

KW - co-ordination chemistry

KW - selenium, ligands

U2 - 10.1021/om500610w

DO - 10.1021/om500610w

M3 - Article

SN - 0276-7333

VL - 33

SP - 3640

EP - 3645

JO - Organometallics

JF - Organometallics

IS - 13

ER -

Exploring the coordination of cyclic selenoureas to gold(I)

Abstract

Keywords

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Datasets

Coinage metal complexes of selenoureas derived from N-heterocyclic carbenes

Research output

Straightforward access to chalcogenoureas derived from N-heterocyclic carbenes and their coordination chemistry

Cite this