Exploiting a substituted dihydrotriazinide as a novel bulky ligand: synthesis and crystal structure of a rubidium complex with an unprecedented tetrameric cyclic core

W Clegg, A M Drummond, Robert Mulvey, P OShaughnessy

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A metal exchange reaction between the alkoxide (BuORb)-O-t and a dihydrotriazinidolithium complex in tetrahydrofuran (thf) has yielded the first reported triazinidorubidium species, in the bis(thf) solvate of 4-n-butyl-4-tert-butyl-2,6-diphenyl-1,4-dihydro-s-triazinido-1-rubidium, which exists as a unique cyclic tetramer in the solid state having an unprecedented sixteen-membered (NCNRb)(4) ring core.

LanguageEnglish
Pages1301-1302
Number of pages2
JournalChemical Communications
Issue number14
DOIs
Publication statusPublished - 21 Jul 1997

Fingerprint

Rubidium
Crystal structure
Ligands
Metals
tetrahydrofuran
diphenyl

Keywords

  • induced cycltrimerization reactions
  • x-rays
  • organic nitriles
  • potassium
  • NMR
  • MO

Cite this

@article{70477ab33d2e4ce0bf4aafb0bbe25e5c,
title = "Exploiting a substituted dihydrotriazinide as a novel bulky ligand: synthesis and crystal structure of a rubidium complex with an unprecedented tetrameric cyclic core",
abstract = "A metal exchange reaction between the alkoxide (BuORb)-O-t and a dihydrotriazinidolithium complex in tetrahydrofuran (thf) has yielded the first reported triazinidorubidium species, in the bis(thf) solvate of 4-n-butyl-4-tert-butyl-2,6-diphenyl-1,4-dihydro-s-triazinido-1-rubidium, which exists as a unique cyclic tetramer in the solid state having an unprecedented sixteen-membered (NCNRb)(4) ring core.",
keywords = "induced cycltrimerization reactions, x-rays, organic nitriles, potassium, NMR, MO",
author = "W Clegg and Drummond, {A M} and Robert Mulvey and P OShaughnessy",
year = "1997",
month = "7",
day = "21",
doi = "10.1039/A703009F",
language = "English",
pages = "1301--1302",
journal = "Chemical Communications",
issn = "1359-7345",
number = "14",

}

Exploiting a substituted dihydrotriazinide as a novel bulky ligand: synthesis and crystal structure of a rubidium complex with an unprecedented tetrameric cyclic core. / Clegg, W ; Drummond, A M ; Mulvey, Robert; OShaughnessy, P .

In: Chemical Communications, No. 14, 21.07.1997, p. 1301-1302.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Exploiting a substituted dihydrotriazinide as a novel bulky ligand: synthesis and crystal structure of a rubidium complex with an unprecedented tetrameric cyclic core

AU - Clegg, W

AU - Drummond, A M

AU - Mulvey, Robert

AU - OShaughnessy, P

PY - 1997/7/21

Y1 - 1997/7/21

N2 - A metal exchange reaction between the alkoxide (BuORb)-O-t and a dihydrotriazinidolithium complex in tetrahydrofuran (thf) has yielded the first reported triazinidorubidium species, in the bis(thf) solvate of 4-n-butyl-4-tert-butyl-2,6-diphenyl-1,4-dihydro-s-triazinido-1-rubidium, which exists as a unique cyclic tetramer in the solid state having an unprecedented sixteen-membered (NCNRb)(4) ring core.

AB - A metal exchange reaction between the alkoxide (BuORb)-O-t and a dihydrotriazinidolithium complex in tetrahydrofuran (thf) has yielded the first reported triazinidorubidium species, in the bis(thf) solvate of 4-n-butyl-4-tert-butyl-2,6-diphenyl-1,4-dihydro-s-triazinido-1-rubidium, which exists as a unique cyclic tetramer in the solid state having an unprecedented sixteen-membered (NCNRb)(4) ring core.

KW - induced cycltrimerization reactions

KW - x-rays

KW - organic nitriles

KW - potassium

KW - NMR

KW - MO

U2 - 10.1039/A703009F

DO - 10.1039/A703009F

M3 - Article

SP - 1301

EP - 1302

JO - Chemical Communications

T2 - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 14

ER -