Abstract
Mixed-alkali-metal metalation of toluene in the presence of TMEDA produces the benzyl complex [(PhCH(2))(4)Li2-xNa2+x(TMEDA)(4)], which has an octagonal ring structure that, in. spite of the 4-fold aggregation, contains Li+ cations complexed by bidentate TMEDA, a situation normally sterically forbidden in, homometallic lithium tetramers.
| Language | English |
|---|---|
| Pages | 4170-4172 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 13 |
| Issue number | 11 |
| DOIs |
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| Publication status | Published - Nov 1994 |
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Keywords
- structural characterisitcs
- crystal structure
- alkali
Cite this
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Expanding the Scope of Lithium Coordination Chemistry by Placing Sodium Nearby: A Mixed Lithium-Sodium Benzyl Compound Having TMEDA-Chelated Li+ Cations in an Unprecedented Tetrameric Environment. / Baker, Daniel R.; Clegg, William; Horsburgh, Lynne; Mulvey, Robert.
In: Organometallics, Vol. 13, No. 11, 11.1994, p. 4170-4172.Research output: Contribution to journal › Comment/debate
TY - JOUR
T1 - Expanding the Scope of Lithium Coordination Chemistry by Placing Sodium Nearby: A Mixed Lithium-Sodium Benzyl Compound Having TMEDA-Chelated Li+ Cations in an Unprecedented Tetrameric Environment
AU - Baker, Daniel R.
AU - Clegg, William
AU - Horsburgh, Lynne
AU - Mulvey, Robert
PY - 1994/11
Y1 - 1994/11
N2 - Mixed-alkali-metal metalation of toluene in the presence of TMEDA produces the benzyl complex [(PhCH(2))(4)Li2-xNa2+x(TMEDA)(4)], which has an octagonal ring structure that, in. spite of the 4-fold aggregation, contains Li+ cations complexed by bidentate TMEDA, a situation normally sterically forbidden in, homometallic lithium tetramers.
AB - Mixed-alkali-metal metalation of toluene in the presence of TMEDA produces the benzyl complex [(PhCH(2))(4)Li2-xNa2+x(TMEDA)(4)], which has an octagonal ring structure that, in. spite of the 4-fold aggregation, contains Li+ cations complexed by bidentate TMEDA, a situation normally sterically forbidden in, homometallic lithium tetramers.
KW - structural characterisitcs
KW - crystal structure
KW - alkali
U2 - 10.1021/om00023a017
DO - 10.1021/om00023a017
M3 - Comment/debate
VL - 13
SP - 4170
EP - 4172
JO - Organometallics
T2 - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 11
ER -