Excited multiplets of Eu in GaN

Benjamin Hourahine

Research output: Contribution to journal › Article

2 Citations (Scopus)

Abstract

A method to calculate the multiplet states of lanthanide impurities in solids is presented. This approach is based on a semi-empirical density functional method which includes corrections to account for the correlation and spin-orbit coupling of the 4f electrons. Specific multiplet states of the rare earth are produced by constraining the system. This approach is then used to investigate some of the properties of substitutional europium impurities in gallium nitride, reproducing the relative energy of two multiplets, and discussing a potential excitation mechanism for these centers.
LanguageEnglish
Pages46-51
Number of pages6
JournalMRS Online Proceedings Library
Volume1290
DOIs
Publication statusPublished - 2011

Fingerprint

fine structure
Impurities
Europium
Lanthanoid Series Elements
Gallium nitride
Rare earth elements
Rare earths
impurities
Orbits
gallium nitrides
europium
Electrons
rare earth elements
orbits
excitation
electrons
energy
gallium nitride

Keywords

  • Eu
  • GaN
  • electronic structure

Cite this

Hourahine, Benjamin. / Excited multiplets of Eu in GaN. In: MRS Online Proceedings Library . 2011 ; Vol. 1290. pp. 46-51.
@article{7bf25718702d4dda858957d3ac9f74de,
title = "Excited multiplets of Eu in GaN",
abstract = "A method to calculate the multiplet states of lanthanide impurities in solids is presented. This approach is based on a semi-empirical density functional method which includes corrections to account for the correlation and spin-orbit coupling of the 4f electrons. Specific multiplet states of the rare earth are produced by constraining the system. This approach is then used to investigate some of the properties of substitutional europium impurities in gallium nitride, reproducing the relative energy of two multiplets, and discussing a potential excitation mechanism for these centers.",
keywords = "Eu, GaN, electronic structure",
author = "Benjamin Hourahine",
note = "Manuscript as accepted by journal for publication. Appeared in a revised form, subsequent to editorial input by Cambridge University Press (c).",
year = "2011",
doi = "10.1557/opl.2011.525",
language = "English",
volume = "1290",
pages = "46--51",
journal = "MRS Online Proceedings Library",
issn = "1946-4274",

}

Hourahine, B 2011, 'Excited multiplets of Eu in GaN' MRS Online Proceedings Library , vol. 1290, pp. 46-51. https://doi.org/10.1557/opl.2011.525

Excited multiplets of Eu in GaN. / Hourahine, Benjamin.

In: MRS Online Proceedings Library , Vol. 1290, 2011, p. 46-51.

Research output: Contribution to journal › Article

TY - JOUR

T1 - Excited multiplets of Eu in GaN

AU - Hourahine, Benjamin

N1 - Manuscript as accepted by journal for publication. Appeared in a revised form, subsequent to editorial input by Cambridge University Press (c).

PY - 2011

Y1 - 2011

N2 - A method to calculate the multiplet states of lanthanide impurities in solids is presented. This approach is based on a semi-empirical density functional method which includes corrections to account for the correlation and spin-orbit coupling of the 4f electrons. Specific multiplet states of the rare earth are produced by constraining the system. This approach is then used to investigate some of the properties of substitutional europium impurities in gallium nitride, reproducing the relative energy of two multiplets, and discussing a potential excitation mechanism for these centers.

AB - A method to calculate the multiplet states of lanthanide impurities in solids is presented. This approach is based on a semi-empirical density functional method which includes corrections to account for the correlation and spin-orbit coupling of the 4f electrons. Specific multiplet states of the rare earth are produced by constraining the system. This approach is then used to investigate some of the properties of substitutional europium impurities in gallium nitride, reproducing the relative energy of two multiplets, and discussing a potential excitation mechanism for these centers.

KW - Eu

KW - GaN

KW - electronic structure

UR - http://www.scopus.com/inward/record.url?scp=84859088993&partnerID=8YFLogxK

UR - http://journals.cambridge.org/action/displayAbstract?fromPage=online&aid=8211475

U2 - 10.1557/opl.2011.525

DO - 10.1557/opl.2011.525

M3 - Article

VL - 1290

SP - 46

EP - 51

JO - MRS Online Proceedings Library

T2 - MRS Online Proceedings Library

JF - MRS Online Proceedings Library

SN - 1946-4274

ER -

Hourahine B. Excited multiplets of Eu in GaN. MRS Online Proceedings Library . 2011;1290:46-51. https://doi.org/10.1557/opl.2011.525

Access to Document

    Related content

    Research Output

    dftbplus/dftbplus [DFTB+]: Release 17.1

    Research output: Non-textual form › Software