Exceptional electron donating ability of an extended tetrathiafulvalene derivative

T. Khan; P.J. Skabara; P. Frere; M. Allain; S.J. Coles; M.B. Hursthouse

doi:10.1016/j.tetlet.2004.02.003

Exceptional electron donating ability of an extended tetrathiafulvalene derivative

T. Khan
, P.J. Skabara
, P. Frere
, M. Allain
, S.J. Coles
, M.B. Hursthouse

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

We report the synthesis, crystal structures and redox chemistry of two new TTF derivatives bearing fused triaryl units. Both compounds show significant planarisation within conjugated regions, assisted by close intramolecular S...O contacts. The extended-TTF analogue displays multi-redox activity and can be oxidised, sequentially to the tetracation species.

Original language	English
Pages (from-to)	2535-2539
Number of pages	4
Journal	Tetrahedron Letters
Volume	45
Issue number	12
DOIs	https://doi.org/10.1016/j.tetlet.2004.02.003
Publication status	Published - 15 Mar 2004

Keywords

tetrathiafulvalene
synthesis
X-ray crystallography
electrochemistry

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10.1016/j.tetlet.2004.02.003

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abstract = "We report the synthesis, crystal structures and redox chemistry of two new TTF derivatives bearing fused triaryl units. Both compounds show significant planarisation within conjugated regions, assisted by close intramolecular S...O contacts. The extended-TTF analogue displays multi-redox activity and can be oxidised, sequentially to the tetracation species.",

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T1 - Exceptional electron donating ability of an extended tetrathiafulvalene derivative

AU - Khan, T.

AU - Skabara, P.J.

AU - Frere, P.

AU - Allain, M.

AU - Coles, S.J.

AU - Hursthouse, M.B.

PY - 2004/3/15

Y1 - 2004/3/15

N2 - We report the synthesis, crystal structures and redox chemistry of two new TTF derivatives bearing fused triaryl units. Both compounds show significant planarisation within conjugated regions, assisted by close intramolecular S...O contacts. The extended-TTF analogue displays multi-redox activity and can be oxidised, sequentially to the tetracation species.

AB - We report the synthesis, crystal structures and redox chemistry of two new TTF derivatives bearing fused triaryl units. Both compounds show significant planarisation within conjugated regions, assisted by close intramolecular S...O contacts. The extended-TTF analogue displays multi-redox activity and can be oxidised, sequentially to the tetracation species.

KW - tetrathiafulvalene

KW - synthesis

KW - X-ray crystallography

KW - electrochemistry

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DO - 10.1016/j.tetlet.2004.02.003

M3 - Article

SN - 0040-4039

VL - 45

SP - 2535

EP - 2539

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 12

ER -

Exceptional electron donating ability of an extended tetrathiafulvalene derivative

Abstract

Keywords

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