Evidence of single electron transfer from the enolate anion of an N,N'-dialkyldiketopiperazine additive in BHAS coupling reactions

Katie J. Emery, Tell Tuttle, John A. Murphy

Research output: Contribution to journalArticle

11 Citations (Scopus)
10 Downloads (Pure)

Abstract

A designed N,N'-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.

Original languageEnglish
Pages (from-to)8810-8819
Number of pages10
JournalOrganic and Biomolecular Chemistry
Volume15
Issue number41
Early online date5 Oct 2017
DOIs
Publication statusPublished - 25 Oct 2017

Keywords

  • electron transfer
  • N,N'-dialkyldiketopiperazine
  • haloarenes

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