Evidence of single electron transfer from the enolate anion of an N,N'-dialkyldiketopiperazine additive in BHAS coupling reactions

Katie J. Emery; Tell Tuttle; John A. Murphy

doi:10.1039/c7ob02209c

Evidence of single electron transfer from the enolate anion of an N,N'-dialkyldiketopiperazine additive in BHAS coupling reactions

Katie J. Emery, Tell Tuttle, John A. Murphy

Pure And Applied Chemistry

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15 Citations (Scopus)

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Abstract

A designed N,N'-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.

Original language	English
Pages (from-to)	8810-8819
Number of pages	10
Journal	Organic and Biomolecular Chemistry
Volume	15
Issue number	41
Early online date	5 Oct 2017
DOIs	https://doi.org/10.1039/c7ob02209c
Publication status	Published - 25 Oct 2017

Keywords

electron transfer
N,N'-dialkyldiketopiperazine
haloarenes

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10.1039/c7ob02209c

Emery-etal-OBC-2017-Evidence-of-single-electron-transfer-from-the-enolate-anionAccepted author manuscript, 5.58 MB

EPSRC Doctoral Training Grant - DTA, University of Strathclyde
McFarlane, A. (Principal Investigator)
EPSRC (Engineering and Physical Sciences Research Council)
1/10/13 → 30/09/17
Project: Research - Studentship

Cite this

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title = "Evidence of single electron transfer from the enolate anion of an N,N'-dialkyldiketopiperazine additive in BHAS coupling reactions",

abstract = "A designed N,N'-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.",

keywords = "electron transfer, N,N'-dialkyldiketopiperazine, haloarenes",

author = "Emery, {Katie J.} and Tell Tuttle and Murphy, {John A.}",

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AU - Emery, Katie J.

AU - Tuttle, Tell

AU - Murphy, John A.

PY - 2017/10/25

Y1 - 2017/10/25

N2 - A designed N,N'-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.

AB - A designed N,N'-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.

KW - electron transfer

KW - N,N'-dialkyldiketopiperazine

KW - haloarenes

U2 - 10.1039/c7ob02209c

DO - 10.1039/c7ob02209c

M3 - Article

C2 - 29022630

SN - 1477-0520

VL - 15

SP - 8810

EP - 8819

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 41

ER -

Evidence of single electron transfer from the enolate anion of an N,N'-dialkyldiketopiperazine additive in BHAS coupling reactions

Abstract

Keywords

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Projects

EPSRC Doctoral Training Grant - DTA, University of Strathclyde

Cite this