Abstract
A designed N,N'-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.
| Language | English |
|---|---|
| Pages | 8810-8819 |
| Number of pages | 10 |
| Journal | Organic and Biomolecular Chemistry |
| Volume | 15 |
| Issue number | 41 |
| Early online date | 5 Oct 2017 |
| DOIs | |
| Publication status | Published - 25 Oct 2017 |
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Keywords
- electron transfer
- N,N'-dialkyldiketopiperazine
- haloarenes
Cite this
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Evidence of single electron transfer from the enolate anion of an N,N'-dialkyldiketopiperazine additive in BHAS coupling reactions. / Emery, Katie J.; Tuttle, Tell; Murphy, John A.
In: Organic and Biomolecular Chemistry, Vol. 15, No. 41, 25.10.2017, p. 8810-8819.Research output: Contribution to journal › Article
TY - JOUR
T1 - Evidence of single electron transfer from the enolate anion of an N,N'-dialkyldiketopiperazine additive in BHAS coupling reactions
AU - Emery, Katie J.
AU - Tuttle, Tell
AU - Murphy, John A.
PY - 2017/10/25
Y1 - 2017/10/25
N2 - A designed N,N'-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.
AB - A designed N,N'-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.
KW - electron transfer
KW - N,N'-dialkyldiketopiperazine
KW - haloarenes
U2 - 10.1039/c7ob02209c
DO - 10.1039/c7ob02209c
M3 - Article
VL - 15
SP - 8810
EP - 8819
JO - Organic and Biomolecular Chemistry
T2 - Organic and Biomolecular Chemistry
JF - Organic and Biomolecular Chemistry
SN - 1477-0520
IS - 41
ER -