Evidence of single electron transfer from the enolate anion of an N,N'-dialkyldiketopiperazine additive in BHAS coupling reactions

Katie J. Emery, Tell Tuttle, John A. Murphy

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

A designed N,N'-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.

LanguageEnglish
Pages8810-8819
Number of pages10
JournalOrganic and Biomolecular Chemistry
Volume15
Issue number41
Early online date5 Oct 2017
DOIs
Publication statusPublished - 25 Oct 2017

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initiators
Anions
electron transfer
Substitution reactions
Electrons
substitutes
anions

Keywords

  • electron transfer
  • N,N'-dialkyldiketopiperazine
  • haloarenes

Cite this

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title = "Evidence of single electron transfer from the enolate anion of an N,N'-dialkyldiketopiperazine additive in BHAS coupling reactions",
abstract = "A designed N,N'-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.",
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author = "Emery, {Katie J.} and Tell Tuttle and Murphy, {John A.}",
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T1 - Evidence of single electron transfer from the enolate anion of an N,N'-dialkyldiketopiperazine additive in BHAS coupling reactions

AU - Emery, Katie J.

AU - Tuttle, Tell

AU - Murphy, John A.

PY - 2017/10/25

Y1 - 2017/10/25

N2 - A designed N,N'-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.

AB - A designed N,N'-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.

KW - electron transfer

KW - N,N'-dialkyldiketopiperazine

KW - haloarenes

U2 - 10.1039/c7ob02209c

DO - 10.1039/c7ob02209c

M3 - Article

VL - 15

SP - 8810

EP - 8819

JO - Organic and Biomolecular Chemistry

T2 - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

SN - 1477-0520

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