Evidence for CH ‥ Li interactions in the solid state structure of dibenzylamido-lithium, and in solutions of it and its complexes: coloured species due to benzyl → lithium charge transfer

D BARR, W CLEGG, Robert Mulvey, R SNAITH

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Abstract

While CH ‥ Li interactions are implicated in the solid-State structure of trimeric dibenzylamidolitium in contrast to those of its dimeric complexes, spectroscopic studies on their coloured solutions linked to predictive MO calculations, provide firm evidence for such interactions, with colours being due to benzyl → Li charge transfer in low-association species.
LanguageEnglish
Pages287-289
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number5
DOIs
Publication statusPublished - 1984

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Lithium
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Keywords

  • solid state structure
  • benzylamido-lithium
  • lithium charge transfer

Cite this

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title = "Evidence for CH ‥ Li interactions in the solid state structure of dibenzylamido-lithium, and in solutions of it and its complexes: coloured species due to benzyl → lithium charge transfer",
abstract = "While CH ‥ Li interactions are implicated in the solid-State structure of trimeric dibenzylamidolitium in contrast to those of its dimeric complexes, spectroscopic studies on their coloured solutions linked to predictive MO calculations, provide firm evidence for such interactions, with colours being due to benzyl → Li charge transfer in low-association species.",
keywords = "solid state structure , benzylamido-lithium , lithium charge transfer",
author = "D BARR and W CLEGG and Robert Mulvey and R SNAITH",
year = "1984",
doi = "10.1039/C39840000287",
language = "English",
pages = "287--289",
journal = "Journal of the Chemical Society, Chemical Communications",
issn = "0022-4936",
number = "5",

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T1 - Evidence for CH ‥ Li interactions in the solid state structure of dibenzylamido-lithium, and in solutions of it and its complexes: coloured species due to benzyl → lithium charge transfer

AU - BARR, D

AU - CLEGG, W

AU - Mulvey, Robert

AU - SNAITH, R

PY - 1984

Y1 - 1984

N2 - While CH ‥ Li interactions are implicated in the solid-State structure of trimeric dibenzylamidolitium in contrast to those of its dimeric complexes, spectroscopic studies on their coloured solutions linked to predictive MO calculations, provide firm evidence for such interactions, with colours being due to benzyl → Li charge transfer in low-association species.

AB - While CH ‥ Li interactions are implicated in the solid-State structure of trimeric dibenzylamidolitium in contrast to those of its dimeric complexes, spectroscopic studies on their coloured solutions linked to predictive MO calculations, provide firm evidence for such interactions, with colours being due to benzyl → Li charge transfer in low-association species.

KW - solid state structure

KW - benzylamido-lithium

KW - lithium charge transfer

U2 - 10.1039/C39840000287

DO - 10.1039/C39840000287

M3 - Article

SP - 287

EP - 289

JO - Journal of the Chemical Society, Chemical Communications

T2 - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

SN - 0022-4936

IS - 5

ER -