Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene

Simone Manzini, César A. Urbina Blanco, David J. Nelson, Albert Poater, Tomas Lebl, Sébastien Meiries, Alexandra M. Z. Slawin, Laura Falivene, Luigi Cavallo, Steven P. Nolan

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Abstract

The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored.
Original languageEnglish
Number of pages66
JournalJournal of Organometallic Chemistry
Early online date9 Jan 2015
DOIs
Publication statusPublished - 2015

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Keywords

  • olefin metathesis
  • metathesis reaction
  • carbene ligands

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