Abstract
The use of a sodium in sodium chloride dispersion is systematically evaluated for the synthesis of nickel(0) and nickel(I) complexes from readily-prepared nickel(II) precursors. A variety of complexes with phosphine and bipyridine-type ligands were accessed, although some reactions were found to produce mixtures of nickel(0) and nickel(I), and yields were highly variable. Several new nickel(I) complexes were obtained, and these were characterized using techniques including NMR spectroscopy, EPR spectroscopy, and single crystal X-ray diffraction analysis.
Original language | English |
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Article number | e202101006 |
Number of pages | 8 |
Journal | European Journal of Inorganic Chemistry |
Volume | 2022 |
Issue number | 7 |
Early online date | 23 Dec 2021 |
DOIs | |
Publication status | Published - 9 Mar 2022 |
Keywords
- low-valent
- nickel
- reduction
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Data for: "Evaluating a Dispersion of Sodium in Sodium Chloride for the Synthesis of Low-Valent Nickel Complexes"
Johnson Humphrey, E. (Creator) & Nelson, D. (Creator), University of Strathclyde, 20 Jan 2022
DOI: 10.15129/950aae01-46ee-44d4-acff-334a6fe1b4d2
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