Ethyl 2-amino-4-isopropyl-1,3-thiazole-5-carboxylate

A.R. Kennedy; A.I. Khalaf; C.J. Suckling; R.D. Waigh

doi:10.1107/S1600536804013984

Ethyl 2-amino-4-isopropyl-1,3-thiazole-5-carboxylate

A.R. Kennedy, A.I. Khalaf, C.J. Suckling, R.D. Waigh

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

In the crystal structure of the title compound, [Mg(C4H8O)2(C9H7)2], the two indenyl ligands are bound to the Mg atom in a manner intermediate between η1- and η3-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)2 adduct (THF is tetrahydrofuran). A crystallographic C2 axis bisects the O-Mg-O angle.

Original language	English
Pages (from-to)	1188-1190
Number of pages	2
Journal	Acta Crystallographica Section E: Structure Reports
Volume	60
Issue number	8
DOIs	https://doi.org/10.1107/S1600536804013984
Publication status	Published - 17 Jul 2004

Keywords

crystal structure
Mg atom
ring-sharing C atoms
crystallographic

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10.1107/S1600536804013984

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title = "Ethyl 2-amino-4-isopropyl-1,3-thiazole-5-carboxylate",

abstract = "In the crystal structure of the title compound, [Mg(C4H8O)2(C9H7)2], the two indenyl ligands are bound to the Mg atom in a manner intermediate between η1- and η3-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)2 adduct (THF is tetrahydrofuran). A crystallographic C2 axis bisects the O-Mg-O angle.",

keywords = "crystal structure, Mg atom, ring-sharing C atoms, crystallographic",

author = "A.R. Kennedy and A.I. Khalaf and C.J. Suckling and R.D. Waigh",

year = "2004",

month = jul,

day = "17",

doi = "10.1107/S1600536804013984",

language = "English",

volume = "60",

pages = "1188--1190",

journal = "Acta Crystallographica Section E: Structure Reports",

issn = "1600-5368",

number = "8",

}

TY - JOUR

T1 - Ethyl 2-amino-4-isopropyl-1,3-thiazole-5-carboxylate

AU - Kennedy, A.R.

AU - Khalaf, A.I.

AU - Suckling, C.J.

AU - Waigh, R.D.

PY - 2004/7/17

Y1 - 2004/7/17

N2 - In the crystal structure of the title compound, [Mg(C4H8O)2(C9H7)2], the two indenyl ligands are bound to the Mg atom in a manner intermediate between η1- and η3-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)2 adduct (THF is tetrahydrofuran). A crystallographic C2 axis bisects the O-Mg-O angle.

AB - In the crystal structure of the title compound, [Mg(C4H8O)2(C9H7)2], the two indenyl ligands are bound to the Mg atom in a manner intermediate between η1- and η3-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)2 adduct (THF is tetrahydrofuran). A crystallographic C2 axis bisects the O-Mg-O angle.

KW - crystal structure

KW - Mg atom

KW - ring-sharing C atoms

KW - crystallographic

UR - http://www.blackwell-synergy.com/doi/full/10.1107/S1600536804016149

U2 - 10.1107/S1600536804013984

DO - 10.1107/S1600536804013984

M3 - Article

SN - 1600-5368

VL - 60

SP - 1188

EP - 1190

JO - Acta Crystallographica Section E: Structure Reports

JF - Acta Crystallographica Section E: Structure Reports

IS - 8

ER -

Ethyl 2-amino-4-isopropyl-1,3-thiazole-5-carboxylate

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Ethyl 2-amino-4-isopropyl-1,3-thiazole-5-carboxylate

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