Ethyl 2-amino-4-isopropyl-1,3-thiazole-5-carboxylate

A.R. Kennedy, A.I. Khalaf, C.J. Suckling, R.D. Waigh

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

In the crystal structure of the title compound, [Mg(C4H8O)2(C9H7)2], the two indenyl ligands are bound to the Mg atom in a manner intermediate between η1- and η3-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)2 adduct (THF is tetra­hydro­furan). A crystallographic C2 axis bisects the O-Mg-O angle.
Original languageEnglish
Pages (from-to)1188-1190
Number of pages2
JournalActa Crystallographica Section E: Structure Reports
Volume60
Issue number8
DOIs
Publication statusPublished - 17 Jul 2004

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Thiazoles
carboxylates
Atoms
tetrahydrofuran
adducts
atoms
Crystal structure
Ligands
ligands
crystal structure
rings

Keywords

  • crystal structure
  • Mg atom
  • ring-sharing C atoms
  • crystallographic

Cite this

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abstract = "In the crystal structure of the title compound, [Mg(C4H8O)2(C9H7)2], the two indenyl ligands are bound to the Mg atom in a manner intermediate between η1- and η3-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)2 adduct (THF is tetra­hydro­furan). A crystallographic C2 axis bisects the O-Mg-O angle.",
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Ethyl 2-amino-4-isopropyl-1,3-thiazole-5-carboxylate. / Kennedy, A.R.; Khalaf, A.I.; Suckling, C.J.; Waigh, R.D.

In: Acta Crystallographica Section E: Structure Reports, Vol. 60, No. 8, 17.07.2004, p. 1188-1190.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Ethyl 2-amino-4-isopropyl-1,3-thiazole-5-carboxylate

AU - Kennedy, A.R.

AU - Khalaf, A.I.

AU - Suckling, C.J.

AU - Waigh, R.D.

PY - 2004/7/17

Y1 - 2004/7/17

N2 - In the crystal structure of the title compound, [Mg(C4H8O)2(C9H7)2], the two indenyl ligands are bound to the Mg atom in a manner intermediate between η1- and η3-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)2 adduct (THF is tetra­hydro­furan). A crystallographic C2 axis bisects the O-Mg-O angle.

AB - In the crystal structure of the title compound, [Mg(C4H8O)2(C9H7)2], the two indenyl ligands are bound to the Mg atom in a manner intermediate between η1- and η3-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)2 adduct (THF is tetra­hydro­furan). A crystallographic C2 axis bisects the O-Mg-O angle.

KW - crystal structure

KW - Mg atom

KW - ring-sharing C atoms

KW - crystallographic

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DO - 10.1107/S1600536804016149

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JO - Acta Crystallographica Section E: Structure Reports

JF - Acta Crystallographica Section E: Structure Reports

SN - 1600-5368

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ER -