(eta(6)-Benzene)dichloro(diallylphenylphosphine)ruthenium(II), the first structurally characterized complex with the diallylphosphine ligand

S.B. Jensen; M.D. Spicer

doi:10.1107/S1600536801015215

(eta(6)-Benzene)dichloro(diallylphenylphosphine)ruthenium(II), the first structurally characterized complex with the diallylphosphine ligand

S.B. Jensen, M.D. Spicer

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The molecule of the title complex, [(eta (6)-C6H6)-{PhP(CH2CH==CH2)(2)}RuCl2], has the classic piano-stool structure. However, it is noted that the Ru-C distances trans to phosphorus are longer than those trans to chloride. Such a manifestation of the trans-influence is not normally so pronounced in eta (6)-arene complexes of this type. This is the first structure containing the diallylphenylphosphine ligand.

Original language	English
Pages (from-to)	o978-o979
Journal	Acta Crystallographica Section E: Structure Reports
Volume	57
Issue number	10
DOIs	https://doi.org/10.1107/S1600536801015215
Publication status	Published - Oct 2001

Keywords

crystallography
[(η6-C6H6){PhP(CH2CH=CH2)2}RuCl2]
diallylphosphine ligand
ruthenium(ii)

Access to Document

10.1107/S1600536801015215

Cite this

@article{b55b759dde6b4eb992b97ad401d23639,

title = "(eta(6)-Benzene)dichloro(diallylphenylphosphine)ruthenium(II), the first structurally characterized complex with the diallylphosphine ligand",

abstract = "The molecule of the title complex, [(eta (6)-C6H6)-\{PhP(CH2CH==CH2)(2)\}RuCl2], has the classic piano-stool structure. However, it is noted that the Ru-C distances trans to phosphorus are longer than those trans to chloride. Such a manifestation of the trans-influence is not normally so pronounced in eta (6)-arene complexes of this type. This is the first structure containing the diallylphenylphosphine ligand.",

keywords = "crystallography, [(η6-C6H6)\{PhP(CH2CH=CH2)2\}RuCl2], diallylphosphine ligand, ruthenium(ii)",

author = "S.B. Jensen and M.D. Spicer",

year = "2001",

month = oct,

doi = "10.1107/S1600536801015215",

language = "English",

volume = "57",

pages = "o978--o979",

journal = "Acta Crystallographica Section E: Structure Reports",

issn = "1600-5368",

number = "10",

}

TY - JOUR

T1 - (eta(6)-Benzene)dichloro(diallylphenylphosphine)ruthenium(II), the first structurally characterized complex with the diallylphosphine ligand

AU - Jensen, S.B.

AU - Spicer, M.D.

PY - 2001/10

Y1 - 2001/10

N2 - The molecule of the title complex, [(eta (6)-C6H6)-{PhP(CH2CH==CH2)(2)}RuCl2], has the classic piano-stool structure. However, it is noted that the Ru-C distances trans to phosphorus are longer than those trans to chloride. Such a manifestation of the trans-influence is not normally so pronounced in eta (6)-arene complexes of this type. This is the first structure containing the diallylphenylphosphine ligand.

AB - The molecule of the title complex, [(eta (6)-C6H6)-{PhP(CH2CH==CH2)(2)}RuCl2], has the classic piano-stool structure. However, it is noted that the Ru-C distances trans to phosphorus are longer than those trans to chloride. Such a manifestation of the trans-influence is not normally so pronounced in eta (6)-arene complexes of this type. This is the first structure containing the diallylphenylphosphine ligand.

KW - crystallography

KW - [(η6-C6H6){PhP(CH2CH=CH2)2}RuCl2]

KW - diallylphosphine ligand

KW - ruthenium(ii)

UR - http://www.blackwell-synergy.com/doi/full/10.1107/S1600536801015215

UR - http://dx.doi.org/10.1107/S1600536801015215

U2 - 10.1107/S1600536801015215

DO - 10.1107/S1600536801015215

M3 - Article

SN - 1600-5368

VL - 57

SP - o978-o979

JO - Acta Crystallographica Section E: Structure Reports

JF - Acta Crystallographica Section E: Structure Reports

IS - 10

ER -

(eta(6)-Benzene)dichloro(diallylphenylphosphine)ruthenium(II), the first structurally characterized complex with the diallylphosphine ligand

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this